Facile Synthesis of Metalloporphyrins-Ba2+ Composites as Recyclable and Efficient Catalysts for Olefins Epoxidation Reactions

doi:10.1007/s40242-019-8348-6

Chemical Research in Chinese Universities ›› 2019, Vol. 35 ›› Issue (2): 251-255.doi: 10.1007/s40242-019-8348-6

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Facile Synthesis of Metalloporphyrins-Ba²⁺ Composites as Recyclable and Efficient Catalysts for Olefins Epoxidation Reactions

HE Qian¹, ZHANG Ying², XIAO Huajian¹, HE Xiaohui¹, ZHOU Xiantai², JI Hongbing¹

1. Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, P. R. China;
2. Fine Chemical Industry Research Institute, School of Chemical Engineering and Technology, Sun Yat-sen University Zhuhai Compus, Zhuhai 519082, P. R. China

Received:2018-10-26 Revised:2018-12-12 Online:2019-04-01 Published:2019-04-30
Contact: HE Xiaohui, JI Hongbing E-mail:hexiaohui@mail.sysu.edu.cn;jihb@mail.sysu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21606260, 21576302, 21376278), the National Science Foundation for Distinguished Young Scholars of China(No.21425627), the Natural Science Foundation of Guangdong Province, China(No.2015A030313104), the Fundamental Research Funds for the Central Universities from Sun Yat-sen University, China(Nos.15lgjc33, 16lgpy15), and the Features Innovative Projects of Department of Education of Guangdong Province, China(No.2016KTSCX003).

Abstract

Abstract: A facile co-precipitation method was developed to prepare the novel metalloporphyrins-Ba²⁺ composites with ca. 3 μm diameter and olive-like morphology. Olefins epoxidation reactions were employed to investigate their catalytic performance. Compared with the free metalloporphyrins, the composites exhibited not only the improved stability and recyclability, but also the enhanced catalytic activity. Such catalytic behaviors could be related to the unique structure of the composites, e.g., the strong interaction between R-SO₃^- and Ba²⁺ ions and the uniform distribution of metalloporphyrins on the catalyst surface, respectively. Furthermore, the composites showed good compatibility with a wide range of substrates. The well-designed composites are expected to be efficient catalysts, alternative to many sophisticated-synthesized metalloporphrins-based materials, in the industrially important reactions.

Key words: Metalloporphyrin, FeTPPS-Ba²⁺, Olefins epoxidation, Catalytic activity, Recyclability

HE Qian, ZHANG Ying, XIAO Huajian, HE Xiaohui, ZHOU Xiantai, JI Hongbing. Facile Synthesis of Metalloporphyrins-Ba²⁺ Composites as Recyclable and Efficient Catalysts for Olefins Epoxidation Reactions[J]. Chemical Research in Chinese Universities, 2019, 35(2): 251-255.

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Facile Synthesis of Metalloporphyrins-Ba²⁺ Composites as Recyclable and Efficient Catalysts for Olefins Epoxidation Reactions

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