Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology

doi:10.1007/s40242-017-7050-9

Abstract

Abstract:

Three layered aluminophosphates(UiO-15, APDAP₁₂-150 and APDAP-150) with same topology were crystallized from an initial mixture with a molar composition of Al₂O₃:1.5P₂O₅:5.5R:227H₂O, where R is ethylenediamine, 1,2-diaminopropane or 1,3-diaminopropane, respectively. The crystallization processes of UiO-15, APDAP₁₂-150 and APDAP-150 were investigated using solid-state NMR in combination with XRD and other characterization techniques. The evolution of the coordination states of Al and P in the solid products was monitored, and the possible starting points of crystallization(core units) of UiO-15, APDAP₁₂-150 and APDAP-150 were obtained and analyzed. The formation of a trimer as well as a hexamer of aluminophosphate, a monomer of PO₄ and a nonamer containing two three-membered rings is critical for the start of crystallization of UiO-15. The formation of a hexamer and a pentamer is critical for the start of crystallization of APDAP₁₂-150. The formation of an AlO₆ monomer and a pentamer containing a three-membered ring is critical for the start of crystallization of APDAP-150. The crystal water played a co-structure-directing role in the formation of APDAP-150.

Key words: Zeolite, Aluminophosphate, Templating effect, Structure-directing effect

WANG Aitian, XU Jun, WANG Chao, DENG Feng, XU Ruren, YAN Wenfu. Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology[J]. Chemical Research in Chinese Universities, 2017, 33(4): 513-519.

References

[1] Xu R. R., Pang W. Q., Yu J. H., Huo Q. S., Chen J. S., Chemistry of Zeolites and Related Porous Materials:Synthesis and Structure, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008
[2] Wright P. A., Microporous Framework Solids, Royal Society of Chemistry, Cambridge, 2008
[3] Chester A. W., Derouane E. G., Zeolite Characterization and Catalysis——A Tutorial, Springer, New York, 2009
[4] Vermeiren W., Gilson J. P., Topics in Catalysis, 2009, 52(9), 1131
[5] Kulprathipanja S., Zeolites in Industrial Separation and Catalysis, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010
[6] Cejka J., Corma A., Zones S., Zeolites and Catalysis:Synthesis, Reactions and Applications, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010
[7] Yu J. H., Xu R. R., Accounts of Chemical Research, 2003, 36(7), 481
[8] Yu J. H., Xu R. R., Chem. Soc. Rev., 2006, 35(7), 593
[9] Wilson S. T., Lok B. M., Flanigen E. M., Crystalline Metallophosphate Compositions, US Pat. 4310440, 1982
[10] Wilson S. T., Lok B. M., Messina C. A., Cannan T. R., Flanigen E. M., J. Am. Chem. Soc., 1982, 104(4), 1146
[11] Cundy C. S., Cox P. A., Micropor. Mesopor. Mater., 2005, 82(1/2), 1
[12] Wilson S. T., Studies in Surface Science and Catalysis, 2001, 137, 229
[13] Lok B. M., Cannan T. R., Messina C. A., Zeolites, 1983, 3(4), 282
[14] Tapp N. J., Milestone N. B., Bibby D. M., Zeolites, 1988, 8(3), 183
[15] Lewis D. W., Freeman C. M., Catlow C. R. A., J. Phys. Chem., 1995, 99(28), 11194
[16] Lewis D. W., Sankar G., Wyles J. K., Thomas J. M., Catlow C. R. A., Willock D. J., Angew. Chem. Int. Ed. Eng., 1997, 36(23), 2675
[17] Nakagawa Y., Lee G. S., Harris T. V., Yuen L. T., Zones S. I., Microporous and Mesoporous Mater., 1998, 22(1-3), 69
[18] Fodor D., Beloqui Redondo A., Krumeich F., van Bokhoven J. A., J. Phys. Chem. C, 2015, 119(10), 5447
[19] Li J., Yu J., Yan W., Xu Y., Xu W., Qiu S., Xu R., Chem. Mater., 1999, 11(9), 2600
[20] Tong X. Q., Xu J., Wang C., Lu H. Y., Huang P., Yan W. F., Yu J. H., Deng F., Xu R. R., Microporous and Mesoporous Mater., 2012, 155, 153
[21] Park M. B., Ahn N. H., Broach R. W., Nicholas C. P., Lewis G. J., Hong S. B., Chem. Mater., 2015, 27(5), 1574
[22] Zhang B., Xu J., Fan F. T., Guo Q., Tong X. Q., Yan W. F., Yu J. H., Deng F., Li C., Xu R. R., Microporous and Mesoporous Mater., 2012, 147(1), 212
[23] Wagner P., Nakagawa Y., Lee G. S., Davis M. E., Elomari S., Medrud R. C., Zones S. I., J. Am. Chem. Soc., 2000, 122(2), 263
[24] Tong X. Q., Xu J., Xin L., Huang P., Lu H. Y., Wang C., Yan W. F., Yu J. H., Deng F., Sun H., Xu R. R., Microporous and Mesoporous Mater., 2012, 164, 56
[25] Sastre G., Leiva S., Sabater M. J., Gimenez I., Rey F., Valencia S., Corma A., J. Phys. Chem. B, 2003, 107(23), 5432
[26] Tong X. Q., Xu J., Li X., Li Y., Yan W. F., Yu J. H., Deng F., Sun H., Xu R. R., Microporous and Mesoporous Mater., 2013, 176, 112
[27] Huang P., Xu J., Wang C., Deng F., Yan W. F., RSC Adv., 2014, 4(73), 39011
[28] Pérez-Pariente J., Gómez-Hortigüela L., Arranz M., Chem. Mater., 2004, 16(17), 3209
[29] Lu H. Y., Yan Y., Tong X. Q., Yan W. F., Yu J. H., Xu R. R., Sci. China Chem., 2013, 57(1), 127
[30] Sastre G., Cantin A., Diaz-Cabañas M. J., Corma A., Chem. Mater., 2005, 17(3), 545
[31] Tong X. Q., Xu J., Wang C., Yan W. F., Yu J. H., Deng F., Xu R. R., Microporous and Mesoporous Mater., 2014, 183, 108
[32] Gómez-Hortigüela L., Márquez-Álvarez C., Corà F., López-Arbeloa F., Pérez-Pariente J., Chem. Mater., 2008, 20(3), 987
[33] Yan W. F., Song X. W., Xu R. R., Microporous and Mesoporous Mater., 2009, 123(1-3), 50
[34] Lu H. Y., Xu J., Gao P., Yan W. F., Deng F., Xu R. R., Microporous and Mesoporous Mater., 2015, 208, 105
[35] Zhang X. Q., Trinh T. T., van Santen R. A., Jansen A. P. J., J. Phys. Chem. C, 2011, 115(19), 9561
[36] Pinar A. B., Gomez-Hortiguela L., Perez-Pariente J., Chem. Mater., 2007, 19(23), 5617
[37] Xin L., Sun H., Xu R. R., Yan W. F., Scientific Reports, 2015, 5, 14940
[38] Huang P., Xu J., Qi G. D., Deng F., Xu R. R., Yan W. F., Scientific Reports, 2016, 6, 22019
[39] Gómez-Hortigüela L., Pérez-Pariente J., Corà F., Chemistry——A European Journal, 2009, 15(6), 1478
[40] Yu J., Li J., Wang K., Xu R., Sugiyama K., Terasaki O., Chem. Mater., 2000, 12(12), 3783
[41] Xu R. S., Shi X. C., Zhang W. P., Xu Y. P., Tian Z. J., Lu X. B., Han X. W., Bao X. H., Phys. Chem. Chem. Phys., 2010, 12(10), 2443
[42] White C. E., Provis J. L., J. Phys. Chem. C, 2012, 116(1), 1619
[43] Lu H. Y., Tong X. Q., Yan Y., Yan W. F., Yu J. H., Xu R. R., Chem. J. Chinese Universities, 2013, 34(7), 1571
[44] Chen Y., Feng L., Chem. Res. Chinese Universities, 2016, 32(6), 895
[45] Wang X., Huang Y., Zhang X., Feng X., Huang W., Chem. Res. Chinese Universities, 2017, 33(1), 12
[46] Kongshaug K. O., Fjellvåg H., Lillerud K. P., J. Mater. Chem., 1999, 9(7), 1591
[47] Tuel A., Gramlich V., Baerlocher C., Microporous and Mesoporous Mater., 2000, 41(1-3), 217
[48] Maeda K., Tuel A., Baerlocher C., J. Chem. Soc., Dalton Transactions, 2000, (14), 2457
[49] Kongshaug K. O., Fjellvåg H., Lillerud K. P., Microporous and Mesoporous Mater., 2000, 38(2/3), 311