Influnence of Sodium Polyacrylate on Crystallization and Aggregation of Butterfly-like Calcium Carbonate

doi:10.1007/s40242-013-3125-4

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (5): 969-973.doi: 10.1007/s40242-013-3125-4

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Influnence of Sodium Polyacrylate on Crystallization and Aggregation of Butterfly-like Calcium Carbonate

ZHAO Li-na^1,2, WANG Ji-ku^1,2, WANG Zi-chen³

1. College of Chemistry, Ministry of Education, Jilin Normal University, Siping 136000, P. R. China;
2. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Siping 136000, P. R. China;
3. College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2013-03-18 Revised:2013-04-17 Online:2013-10-01 Published:2013-09-17
Contact: ZHAO Li-na E-mail:zhaolina1975@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21077041), "the Twelfth Five" Science Technology Research of Jilin Education Hall, China(No.2013[204]) and the Scientific Research Innovation Plan for Young Talented Person of Jilin Normal University, China(No.2011[05]).

Abstract

Abstract:

Butterfly-like calcium carbonate(CaCO₃) particles were successfully prepared via a facile precipitation reaction of Na₂CO₃ with CaCl₂ in the presence of sodium polyacrylate(PAAS). The as-prepared samples were characterized with field emission scanning electron microscopy(FESEM), X-ray diffraction(XRD) and Fourier transform infrared spectroscopy(FTIR). Butterfly-like CaCO₃ particles composed of three segment rods were obtained. Rod aggregates would act as the template for butterfly-like CaCO₃crystals consisted of regular shaped crystallites with 150―200 nm in diameter. The influences of reaction temperature, the amount of PAAS and reaction time on the nucleation and growth of CaCO₃ crystals were investigated. The possible growth mechanism of CaCO₃ crystals was discussed. This research can not only make us further understand the general principles of the reaction, but also open up a new avenue of industrial production of CaCO₃ particles with exquisite and unique morphologies.

Key words: Butterfly-like calcium carbonate, Aragonite, Sodium polyacrylate(PAAS), Crystallization

ZHAO Li-na, WANG Ji-ku, WANG Zi-chen. Influnence of Sodium Polyacrylate on Crystallization and Aggregation of Butterfly-like Calcium Carbonate[J]. Chemical Research in Chinese Universities, 2013, 29(5): 969-973.

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Influnence of Sodium Polyacrylate on Crystallization and Aggregation of Butterfly-like Calcium Carbonate

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