Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber

doi:10.1007/s40242-013-2236-2

Abstract

Abstract:

A proline functionalized fiber catalyst was employed for aldol reactions in water. In the presence of the fiber catalyst, the aldol reactions proceeded smoothly at 40℃ and the products were obtained in excellent yields which were higher than those obtained for the reactions catalyzed by L-proline or trans-4-hydroxy-L-proline. This newly developed fiber catalyst is applicable to the reactions of a wide range of aromatic aldehydes and exhibits excellent reusability(up to 6 times) without any additional treatment.

Key words: Polyacrylonitrile fiber(PANF), Proline, Aldol reaction, Supported catalyst

XIAO Jia, LI Guo-wei, ZHANG Wen-qin. Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber[J]. Chemical Research in Chinese Universities, 2013, 29(2): 256-262.

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