Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H3NC2H4NH2]VOPO4

高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (3): 249-252.

Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H₃NC₂H₄NH₂]VOPO₄

ZHANG Dong, SHI Zhan, FENG Shou-hua

National Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130023, P. R. China

收稿日期:2001-04-19 出版日期:2001-08-24 发布日期:2011-08-04
基金资助:
Supported by the National Natural Science Foundation of China.

Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H₃NC₂H₄NH₂]VOPO₄

ZHANG Dong, SHI Zhan, FENG Shou-hua

National Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130023, P. R. China

Received:2001-04-19 Online:2001-08-24 Published:2011-08-04
Supported by:
Supported by the National Natural Science Foundation of China.

摘要/Abstract

摘要： An inorganic-organic hybrid compound, [H₃NC₂H₄NH₂]VOPO₄ was synthesized by meansof the hydrothermal method.It was crystallized in a monoclinic system, a space group P2₁/c,with the crystal cell parameters: a=0.922 85(11) nm, b=0.729 94(9) nm, c=0.984 95(11)nm, β=101.280(3)°, V=0.650 67(13) nm³, M_r=223.02 g/mol, D_c=2.277 g/cm³, Z=4,R= 0.031 5, ωR= 0.086 5, GOF = 1.085.The VO₅N octahedra chains are corner-linked byPO₄ tetrahedra; the VO₅N octahedra are all trans-linked with V-O bonds being alternately short and long.The monoprotonated ethylenediamine was intercalated between the layers with one end coordinating to V and the other end as an H-bond donor interacting with a terminal O atom of PO₄ from a neighboring sheet.The elementary analysis, infrared spectrum characters and thermal stability were also given.

关键词: Inorganic-organic hybrid material, Hydrothermal synthesis, Vanadium phosphate, Crystal structure

Abstract: An inorganic-organic hybrid compound, [H₃NC₂H₄NH₂]VOPO₄ was synthesized by meansof the hydrothermal method.It was crystallized in a monoclinic system, a space group P2₁/c,with the crystal cell parameters: a=0.922 85(11) nm, b=0.729 94(9) nm, c=0.984 95(11)nm, β=101.280(3)°, V=0.650 67(13) nm³, M_r=223.02 g/mol, D_c=2.277 g/cm³, Z=4,R= 0.031 5, ωR= 0.086 5, GOF = 1.085.The VO₅N octahedra chains are corner-linked byPO₄ tetrahedra; the VO₅N octahedra are all trans-linked with V-O bonds being alternately short and long.The monoprotonated ethylenediamine was intercalated between the layers with one end coordinating to V and the other end as an H-bond donor interacting with a terminal O atom of PO₄ from a neighboring sheet.The elementary analysis, infrared spectrum characters and thermal stability were also given.

Key words: Inorganic-organic hybrid material, Hydrothermal synthesis, Vanadium phosphate, Crystal structure

ZHANG Dong, SHI Zhan, FENG Shou-hua. Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H₃NC₂H₄NH₂]VOPO₄[J]. 高等学校化学研究, 2001, 17(3): 249-252.

ZHANG Dong, SHI Zhan, FENG Shou-hua. Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H₃NC₂H₄NH₂]VOPO₄[J]. Chemical Research in Chinese Universities, 2001, 17(3): 249-252.

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Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H₃NC₂H₄NH₂]VOPO₄

Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H₃NC₂H₄NH₂]VOPO₄

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