Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance

doi:10.1007/s40242-019-9138-x

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 848-853.doi: 10.1007/s40242-019-9138-x

Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance

MA Xiao^1,2, WANG Xiaohong², SHANG Fan², DING Zimei¹, HANG Xiaojing¹, HUANG Jie¹

1. Department of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2. Xi'an Institute of Modern Chemistry, Xi'an 710065, P. R. China

收稿日期:2019-05-17 出版日期:2019-10-01 发布日期:2019-09-24
通讯作者: HUANG Jie E-mail:huangjie@nwu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21241003) and the Natural Science Foundation of Shaanxi Province, China(No.2018JM2061).

Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance

MA Xiao^1,2, WANG Xiaohong², SHANG Fan², DING Zimei¹, HANG Xiaojing¹, HUANG Jie¹

1. Department of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2. Xi'an Institute of Modern Chemistry, Xi'an 710065, P. R. China

Received:2019-05-17 Online:2019-10-01 Published:2019-09-24
Contact: HUANG Jie E-mail:huangjie@nwu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21241003) and the Natural Science Foundation of Shaanxi Province, China(No.2018JM2061).

摘要/Abstract

摘要： The structure of 4-amino-3-(5-tetrazolate)-furazan(HAFT) was characterized by single crystal X-ray diffraction. The thermal decomposition process of HAFT was investigated by MS-FTIR-DSC-TG coupling technique. The result shows that the exothermic process occurs from 278.7-350℃, with a peak temperature of 324.7℃. The thermal decomposition gaseous products of HAFT are NO₂, CO₂, HCN, CO, NH₃ and H₂O. The detonation velocity and detonation pressure of HAFT were calculated by the nitrogen equivalent equation. The detonation velocity of HAFT is 7727.46 m/s, which is higher than that of TNT(7178 m/s). The detonation pressure of HAFT(25.27 GPa) is satisfactory. The sensitivity tests reveal HAFT possesses excellent insensitivities to impact and friction.

关键词: 3-Amino-4-(1H-tetrazol-5-yl)-furazan, Crystal structure, Thermal behavior, Gas product, Energetic performance

Abstract: The structure of 4-amino-3-(5-tetrazolate)-furazan(HAFT) was characterized by single crystal X-ray diffraction. The thermal decomposition process of HAFT was investigated by MS-FTIR-DSC-TG coupling technique. The result shows that the exothermic process occurs from 278.7-350℃, with a peak temperature of 324.7℃. The thermal decomposition gaseous products of HAFT are NO₂, CO₂, HCN, CO, NH₃ and H₂O. The detonation velocity and detonation pressure of HAFT were calculated by the nitrogen equivalent equation. The detonation velocity of HAFT is 7727.46 m/s, which is higher than that of TNT(7178 m/s). The detonation pressure of HAFT(25.27 GPa) is satisfactory. The sensitivity tests reveal HAFT possesses excellent insensitivities to impact and friction.

Key words: 3-Amino-4-(1H-tetrazol-5-yl)-furazan, Crystal structure, Thermal behavior, Gas product, Energetic performance

MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance[J]. 高等学校化学研究, 2019, 35(5): 848-853.

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Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance

Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance

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