Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives

doi:10.1007/s40242-019-9099-0

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 762-766.doi: 10.1007/s40242-019-9099-0

Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives

WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun

Key Laboratory for Advanced Catalysis Materials, Ministry of Education, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, P. R. China

收稿日期:2019-04-08 出版日期:2019-10-01 发布日期:2019-09-24
通讯作者: WANG Dongmei E-mail:dmwang@zjnu.edu.cn
基金资助:
Supported by the Natural Science Foundation of Zhejiang Province, China(No.LQ18B010002).

Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives

WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun

Key Laboratory for Advanced Catalysis Materials, Ministry of Education, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, P. R. China

Received:2019-04-08 Online:2019-10-01 Published:2019-09-24
Contact: WANG Dongmei E-mail:dmwang@zjnu.edu.cn
Supported by:
Supported by the Natural Science Foundation of Zhejiang Province, China(No.LQ18B010002).

摘要/Abstract

摘要： Two isostructural metal-organic frameworks,[NO₃] [M₃(H₂O)₃O(TBA)₃]·2DMF·6H₂O(1 and 2)[M=In and Fe, H₂TBA=4-(1H-tetrazol-5-yl)-benzoic acid], have been successfully synthesized. Compounds 1 and 2 have three-dimensional structures bridged via the typical 6-connected tri-nuclear cluster units M₃O(COO)₆ and linear linker H₂TBA. The whole 3D framework possesses a 6-connected acs topology. Notably, by the fluorescence technique, compound 1 can detect nitro explosives through fluorescence quenching effect, especially for 2,4,6-trinitrophenol(TNP, K_sv=3.64×10⁴ L/mol). Furthermore, the fluorescence spectrum red shifts as the number of-NO₂ group increases. Based on the aforementioned consideration, compound 1 can be considered as a potential luminescent probe for the detection of TNP.

关键词: Metal-organic framework, Crystal structure, Fluorescence detection, Nitro explosive

Abstract: Two isostructural metal-organic frameworks,[NO₃] [M₃(H₂O)₃O(TBA)₃]·2DMF·6H₂O(1 and 2)[M=In and Fe, H₂TBA=4-(1H-tetrazol-5-yl)-benzoic acid], have been successfully synthesized. Compounds 1 and 2 have three-dimensional structures bridged via the typical 6-connected tri-nuclear cluster units M₃O(COO)₆ and linear linker H₂TBA. The whole 3D framework possesses a 6-connected acs topology. Notably, by the fluorescence technique, compound 1 can detect nitro explosives through fluorescence quenching effect, especially for 2,4,6-trinitrophenol(TNP, K_sv=3.64×10⁴ L/mol). Furthermore, the fluorescence spectrum red shifts as the number of-NO₂ group increases. Based on the aforementioned consideration, compound 1 can be considered as a potential luminescent probe for the detection of TNP.

Key words: Metal-organic framework, Crystal structure, Fluorescence detection, Nitro explosive

WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives[J]. 高等学校化学研究, 2019, 35(5): 762-766.

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Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives

Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives

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