Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid

doi:10.1007/s40242-018-8169-z

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (6): 959-964.doi: 10.1007/s40242-018-8169-z

Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid

CHEN Xiang¹, ZENG Tian¹, ZHANG Cong¹, GUO Zhaoqi¹, LI Shuailei¹, MAI Tao¹, GAO Rong², MA Haixia¹

1. School of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2. College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P. R. China

收稿日期:2018-05-21 出版日期:2018-12-01 发布日期:2018-08-03
通讯作者: MA Haixia E-mail:mahx@nwu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21673179, 21504067) and the National Students' Innovation and Entrepreneurship Training Program, China(No.201710697038).

Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid

CHEN Xiang¹, ZENG Tian¹, ZHANG Cong¹, GUO Zhaoqi¹, LI Shuailei¹, MAI Tao¹, GAO Rong², MA Haixia¹

1. School of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2. College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P. R. China

Received:2018-05-21 Online:2018-12-01 Published:2018-08-03
Contact: MA Haixia E-mail:mahx@nwu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21673179, 21504067) and the National Students' Innovation and Entrepreneurship Training Program, China(No.201710697038).

摘要/Abstract

摘要： Two energetic salts, DPHT·DNS·H₂O(1) and DHT·2DNS·2H₂O(2)[DPHT=3-(3,5-dimethyl-1H-pyrazol-1-yl)-6-hydrazinyl-1,2,4,5-tetrazine; DHT=3,6-dihydrazinyl-1,2,4,5-tetrazine], were synthesized from S-tetrazine with 3,5-dinitrosalicylic acid(DNS). Compounds 1 and 2 were structurally characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction. The thermal behavior of the title compounds was studied by differential scanning calorimetry(DSC) and thermogravimetry(TG). The non-isothermal decomposition kinetics of compound 2 were investigated. The self-accelerating decomposition temperature, thermal ignition temperature, and critical temperatures of thermal explosion were obtained to evaluate the thermal safety of compound 2. The results show compounds 1 and 2 decompose at 150.8 and 179.2℃, respectively. The T_SADT and T_b of compound 2 are higher than those of DHT, which indicates compound 2 is a potential candidate for energetic materials that have good thermal stability.

关键词: Tetrazine compound, Dinitrosalicylic acid(DNS), Crystal structure, Thermal behavior, Thermal safety

Abstract: Two energetic salts, DPHT·DNS·H₂O(1) and DHT·2DNS·2H₂O(2)[DPHT=3-(3,5-dimethyl-1H-pyrazol-1-yl)-6-hydrazinyl-1,2,4,5-tetrazine; DHT=3,6-dihydrazinyl-1,2,4,5-tetrazine], were synthesized from S-tetrazine with 3,5-dinitrosalicylic acid(DNS). Compounds 1 and 2 were structurally characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction. The thermal behavior of the title compounds was studied by differential scanning calorimetry(DSC) and thermogravimetry(TG). The non-isothermal decomposition kinetics of compound 2 were investigated. The self-accelerating decomposition temperature, thermal ignition temperature, and critical temperatures of thermal explosion were obtained to evaluate the thermal safety of compound 2. The results show compounds 1 and 2 decompose at 150.8 and 179.2℃, respectively. The T_SADT and T_b of compound 2 are higher than those of DHT, which indicates compound 2 is a potential candidate for energetic materials that have good thermal stability.

Key words: Tetrazine compound, Dinitrosalicylic acid(DNS), Crystal structure, Thermal behavior, Thermal safety

CHEN Xiang, ZENG Tian, ZHANG Cong, GUO Zhaoqi, LI Shuailei, MAI Tao, GAO Rong, MA Haixia. Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid[J]. 高等学校化学研究, 2018, 34(6): 959-964.

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Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid

Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid

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