Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand

doi:10.1007/s40242-017-6366-9

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (1): 44-48.doi: 10.1007/s40242-017-6366-9

Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand

HE Yuanchun¹, GUO Jiao², XU Na¹, YU Yang¹

1. College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, P. R. China;
2. College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang 453003, P. R. China

收稿日期:2016-09-01 修回日期:2016-11-22 出版日期:2017-02-01 发布日期:2016-12-12
通讯作者: HE Yuanchun,E-mail:heyc240@nenu.edu.cn E-mail:heyc240@nenu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21601104, 21501108), the Natural Science Foundation of Shandong Province, China(No.ZR2016BQ19), the Science and Technology Plan Project for Colleges and Universities in Shandong Province, China(No.J16LC01), the Doctoral Foundation of Shandong Province, China(No.BS2014NJ015), and the Scientific Research Foundation of Qufu Normal University, China(No.xkj201604).

Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand

HE Yuanchun¹, GUO Jiao², XU Na¹, YU Yang¹

1. College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, P. R. China;
2. College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang 453003, P. R. China

Received:2016-09-01 Revised:2016-11-22 Online:2017-02-01 Published:2016-12-12
Contact: HE Yuanchun,E-mail:heyc240@nenu.edu.cn E-mail:heyc240@nenu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21601104, 21501108), the Natural Science Foundation of Shandong Province, China(No.ZR2016BQ19), the Science and Technology Plan Project for Colleges and Universities in Shandong Province, China(No.J16LC01), the Doctoral Foundation of Shandong Province, China(No.BS2014NJ015), and the Scientific Research Foundation of Qufu Normal University, China(No.xkj201604).

摘要/Abstract

摘要：

Five coordination polymers,[Co(H₃L)₂(dib)]·1.5H₂O(1),[Cu(H₃L)₂(dib)](2),[Co(H2L)(mtpy)]·DMF(3),[Ni(H₃L)₂(mtpy)(H₂O)]·3DMF·H₂O(4), and[Cd(H₃L)₂(pybim)]·1.5H₂O(5), have been successfully prepared from 5,11,17,23-tetra-tert-butyl-25-(carboxymethoxy)calix[4]arene, metal salts, and N-donor auxiliary ligands under hy-drothermal conditions[dib=1,4-di(1H-imidazol-1-yl)butane, pybim=2-(2'-pyridyl)benzimidazole, and mtpy=4'-(4-methylphenyl)-2,2':6',2"-terpyridine]. Structural analysis suggests that the metal ion first joins two organic carboxylate ligands to form the independent units, which are further extended by the N-donor auxiliary ligand to give the final structure. Compounds 1 and 2 display 1D infinite chains bridged by a flexible bidentate dib ligand. Compounds 3-5, with multidentate chelate ligands, reveal discrete 0D units. Furthermore, in compounds 3 and 5, 1D supramolecular architectures are exhibited due to π-π interactions.

关键词: Calix[4]arene, Crystal structure, Auxiliary ligand

Abstract:

Key words: Calix[4]arene, Crystal structure, Auxiliary ligand

HE Yuanchun, GUO Jiao, XU Na, YU Yang. Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand[J]. 高等学校化学研究, 2017, 33(1): 44-48.

HE Yuanchun, GUO Jiao, XU Na, YU Yang. Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand[J]. Chemical Research in Chinese Universities, 2017, 33(1): 44-48.

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Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand

Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand

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