Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)3]·ZTO·6H2O and[Cu(phen)3]·ZTO·6H2O

doi:10.1007/s40242-018-8051-z

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (6): 1009-1013.doi: 10.1007/s40242-018-8051-z

Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O

DING Zimei¹, CAO Wenli¹, ZHENG Hui¹, HUANG Jie¹, XU Kangzhen¹, SONG Jirong^1,2

1. Department of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2. Conservation Technology Department, the Palace Museum, Beijing 100009, P. R. China

收稿日期:2018-02-04 出版日期:2018-12-01 发布日期:2018-08-03
通讯作者: HUANG Jie E-mail:huangjie@nwu.edu.cn
基金资助:
Supported by the Northwest University Graduate Innovation and Creativity Fund, China(No.YZZ17145) and the Natural Science Basic Research Fund of Shaanxi Province, China(No.2018JM2061).

Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O

DING Zimei¹, CAO Wenli¹, ZHENG Hui¹, HUANG Jie¹, XU Kangzhen¹, SONG Jirong^1,2

1. Department of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2. Conservation Technology Department, the Palace Museum, Beijing 100009, P. R. China

Received:2018-02-04 Online:2018-12-01 Published:2018-08-03
Contact: HUANG Jie E-mail:huangjie@nwu.edu.cn
Supported by:
Supported by the Northwest University Graduate Innovation and Creativity Fund, China(No.YZZ17145) and the Natural Science Basic Research Fund of Shaanxi Province, China(No.2018JM2061).

摘要/Abstract

摘要： [Zn(phen)₃]·ZTO·6H₂O(1) and[Cu(phen)₃]·ZTO·6H₂O(2) were synthesized by the reaction of Zn(NO₃)₂·6H₂O/Cu(NO₃)₂·3H₂O with 4,4-azo-1H-1,2,4-triazol-5-one(ZTO) and 1,10-phenanthroline(phen). The two compounds were characterized by elemental analysis and IR spectrum analysis, respectively. Compound 1 was also characterized by single crystal X-ray diffraction analysis. For compound 1, the coordination geometry around the Zn²⁺ is a distorted octahedron, with the bite angles of 76.7(3)°-77.6(4)° for all three phen ligands. Moreover, the thermal behaviors and thermal decomposition kinetics were studied and analyzed. Besides, thermal stability and safety parameters(T_SADT, T_b) are 164.7 and 166.4℃ for compound 1, and 149.6 and 150.8℃ for compound 2, respectively.

关键词: Azo-triazole, [Zn(phen)₃]·ZTO·, 6H₂O, [Cu(phen)₃]·ZTO·, 6H₂O, Crystal structure, Thermal behavior

Abstract: [Zn(phen)₃]·ZTO·6H₂O(1) and[Cu(phen)₃]·ZTO·6H₂O(2) were synthesized by the reaction of Zn(NO₃)₂·6H₂O/Cu(NO₃)₂·3H₂O with 4,4-azo-1H-1,2,4-triazol-5-one(ZTO) and 1,10-phenanthroline(phen). The two compounds were characterized by elemental analysis and IR spectrum analysis, respectively. Compound 1 was also characterized by single crystal X-ray diffraction analysis. For compound 1, the coordination geometry around the Zn²⁺ is a distorted octahedron, with the bite angles of 76.7(3)°-77.6(4)° for all three phen ligands. Moreover, the thermal behaviors and thermal decomposition kinetics were studied and analyzed. Besides, thermal stability and safety parameters(T_SADT, T_b) are 164.7 and 166.4℃ for compound 1, and 149.6 and 150.8℃ for compound 2, respectively.

Key words: Azo-triazole, [Zn(phen)₃]·ZTO·, 6H₂O, [Cu(phen)₃]·ZTO·, 6H₂O, Crystal structure, Thermal behavior

DING Zimei, CAO Wenli, ZHENG Hui, HUANG Jie, XU Kangzhen, SONG Jirong. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O[J]. 高等学校化学研究, 2018, 34(6): 1009-1013.

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Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O

Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O

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