Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy

doi:10.1007/s40242-020-0152-9

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (6): 1161-1167.doi: 10.1007/s40242-020-0152-9

Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy

ZHANG Wenqi¹, LIN Zhengguo¹, CHI Yingnan¹, HONG Jie², YAN Li², HU Changwen¹

1. Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. Analysis and Testing Center, Beijing Institute of Technology, Beijing 100081, P. R. China

收稿日期:2020-05-14 修回日期:2020-05-21 出版日期:2020-12-01 发布日期:2020-12-03
通讯作者: LIN Zhengguo, HU Changwen E-mail:linzhengguo11@163.com;cwhu@bit.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21871026, 21671019, 21701010).

Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy

ZHANG Wenqi¹, LIN Zhengguo¹, CHI Yingnan¹, HONG Jie², YAN Li², HU Changwen¹

1. Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. Analysis and Testing Center, Beijing Institute of Technology, Beijing 100081, P. R. China

Received:2020-05-14 Revised:2020-05-21 Online:2020-12-01 Published:2020-12-03
Contact: LIN Zhengguo, HU Changwen E-mail:linzhengguo11@163.com;cwhu@bit.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21871026, 21671019, 21701010).

摘要/Abstract

摘要： Three novel scandium-containing heteropolytungstates[Sc₃(H₂O)₃NO₃(PW₉O₃₄)₂]^10-(1a),[Sc₈(H₂O)₂(GeW₉O₃₄)₂(GeW₆O₂₆)₂]^12-(2a) and[Sc₁₁(W₆O₁₀)₂(OH)₂(H₂O)₁₆(BiW₉O₃₃)₆]^27-(3a) were synthesized by reactions of Sc^III ions with trilacunary Keggin precursors,[A-α-XW₉O₃₄]^n-(X=P, Ge, n=9, 10) or[B-α-BiW₉O₃₃]^9-, in NaOAc/HOAc buffer solution under conventional synthetic condition, respectively. All the three compounds were characterized by means of single-crystal X-ray diffraction(XRD), Fourier transform-infrared(FTIR) spectroscopy ultraviolet-visible(UV-Vis) spectroscopy, elemental analysis, and thermogravimetric analysis. The aqueous solution stability of the sandwich polyanion[Sc₃(H₂O)₃NO₃(PW₉O₃₄)₂]^10- was also verified by electrospray ionization mass spectrometry(ESI-MS) due to its good solubility in water.

关键词: Scandium, Heteropolytungstate, Building-block, Crystal structure

Abstract: Three novel scandium-containing heteropolytungstates[Sc₃(H₂O)₃NO₃(PW₉O₃₄)₂]^10-(1a),[Sc₈(H₂O)₂(GeW₉O₃₄)₂(GeW₆O₂₆)₂]^12-(2a) and[Sc₁₁(W₆O₁₀)₂(OH)₂(H₂O)₁₆(BiW₉O₃₃)₆]^27-(3a) were synthesized by reactions of Sc^III ions with trilacunary Keggin precursors,[A-α-XW₉O₃₄]^n-(X=P, Ge, n=9, 10) or[B-α-BiW₉O₃₃]^9-, in NaOAc/HOAc buffer solution under conventional synthetic condition, respectively. All the three compounds were characterized by means of single-crystal X-ray diffraction(XRD), Fourier transform-infrared(FTIR) spectroscopy ultraviolet-visible(UV-Vis) spectroscopy, elemental analysis, and thermogravimetric analysis. The aqueous solution stability of the sandwich polyanion[Sc₃(H₂O)₃NO₃(PW₉O₃₄)₂]^10- was also verified by electrospray ionization mass spectrometry(ESI-MS) due to its good solubility in water.

Key words: Scandium, Heteropolytungstate, Building-block, Crystal structure

ZHANG Wenqi, LIN Zhengguo, CHI Yingnan, HONG Jie, YAN Li, HU Changwen. Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy[J]. 高等学校化学研究, 2020, 36(6): 1161-1167.

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Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy

Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy

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