Synthesis and Crystal Structure of p-tert-Butylcalix[4]arene 1,3-Distal and Monosubstituted Semicarbazones and Thiosemicarbazones

doi:10.1007/s40242-014-3282-0

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (3): 415-419.doi: 10.1007/s40242-014-3282-0

Synthesis and Crystal Structure of p-tert-Butylcalix[4]arene 1,3-Distal and Monosubstituted Semicarbazones and Thiosemicarbazones

LIU Zhenming¹, LIU Dongmei², WANG Jinxiang², SUN Jing², YAN Chaoguo²

1. Analysis and Test Center, Yangzhou University, Yangzhou 225002, P. R. China;
2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

收稿日期:2013-06-08 修回日期:2013-07-30 出版日期:2014-06-01 发布日期:2014-05-12
通讯作者: YAN Chaoguo E-mail:cgyan@yzu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20972132) and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

Synthesis and Crystal Structure of p-tert-Butylcalix[4]arene 1,3-Distal and Monosubstituted Semicarbazones and Thiosemicarbazones

LIU Zhenming¹, LIU Dongmei², WANG Jinxiang², SUN Jing², YAN Chaoguo²

1. Analysis and Test Center, Yangzhou University, Yangzhou 225002, P. R. China;
2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

Received:2013-06-08 Revised:2013-07-30 Online:2014-06-01 Published:2014-05-12
Contact: YAN Chaoguo E-mail:cgyan@yzu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.20972132) and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

摘要/Abstract

摘要：

A series of p-tert-butylcalix[4]arene 1,3-distal and monosubstituted semicarbazones and thiosemi-carbazones was preparedd by acid catalyzed condensation reaction of active calixarene aldehydes with semi-carbazide and thiocarbazide in methanol. One representative single crystal was determined by X-ray dirraction method, which shows that calixarene exists in cone configuration and intramolecular hydrogen-bands exist in the crystal.

关键词: Calixarene, Semicarbazide, Semicarbazone, Thiosemicarbazone, Schiff base, Crystal structure

Abstract:

Key words: Calixarene, Semicarbazide, Semicarbazone, Thiosemicarbazone, Schiff base, Crystal structure

LIU Zhenming, LIU Dongmei, WANG Jinxiang, SUN Jing, YAN Chaoguo. Synthesis and Crystal Structure of p-tert-Butylcalix[4]arene 1,3-Distal and Monosubstituted Semicarbazones and Thiosemicarbazones[J]. 高等学校化学研究, 2014, 30(3): 415-419.

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Synthesis and Crystal Structure of p-tert-Butylcalix[4]arene 1,3-Distal and Monosubstituted Semicarbazones and Thiosemicarbazones

Synthesis and Crystal Structure of p-tert-Butylcalix[4]arene 1,3-Distal and Monosubstituted Semicarbazones and Thiosemicarbazones

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