Syntheses, Crystal Structures and Luminescent Properties of Three New Gallium Complexes Containing Pyridine-2,6-dicarboxylic Acid

高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (6): 936-941.

Syntheses, Crystal Structures and Luminescent Properties of Three New Gallium Complexes Containing Pyridine-2,6-dicarboxylic Acid

ZHOU Guang-peng, YANG Yu-lin, FAN Rui-qing

Department of Chemistry, Harbin Institute of Technology, Harbin 150001, P. R. China

收稿日期:2011-12-19 修回日期:2012-02-01 出版日期:2012-11-25 发布日期:2012-11-09
通讯作者: YANG Yu-lin, FAN Rui-qing E-mail:ylyang@hit.edu.cn;fanruiqing@163.com
基金资助:
Supported by the National Natural Science Foundation of China(Nos.20971031, 21071035, 21171044), the China Postdoctoral Science Foundation Funded Project(No.65204) and the Key Natural Science Foundation of Heilongjiang Province, China(No.ZD201009).

Syntheses, Crystal Structures and Luminescent Properties of Three New Gallium Complexes Containing Pyridine-2,6-dicarboxylic Acid

ZHOU Guang-peng, YANG Yu-lin, FAN Rui-qing

Department of Chemistry, Harbin Institute of Technology, Harbin 150001, P. R. China

Received:2011-12-19 Revised:2012-02-01 Online:2012-11-25 Published:2012-11-09
Contact: YANG Yu-lin, FAN Rui-qing E-mail:ylyang@hit.edu.cn;fanruiqing@163.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20971031, 21071035, 21171044), the China Postdoctoral Science Foundation Funded Project(No.65204) and the Key Natural Science Foundation of Heilongjiang Province, China(No.ZD201009).

摘要/Abstract

摘要：

Three new gallium complexes formulated as [Ga(PDA)₂][Ga(H₂O)(PDA)(phen)]·4H₂O(1), [Ga(PDA)₂]· (H₂IN)·2H₂O(2) and [Ga(OH)(PDA)(H₂O)]₂(3)(H₂PDA=pyridine-2,6-dicarboxylic acid; phen=1,10-phenanthroline; HIN=isonicotinic acid) have been synthesized under hydrothermal conditions. In the mixed-ligand system of complex 1, PDA^2? and phen are connected to the central Ga³⁺ cation as tri- and bi-dentate ligands, respectively. In complex 2, each Ga³⁺ cation is six-coordinated by two PDA^2? anions octahedrally. Complex 3 shows a binuclear structure, with the bond distance of Ga1-Ga2 being 0.30061(3) nm. The 3D supramolecular structures of the three complexes are constructed via hydrogen bonds and aromatic π-π packing interactions. All the three complexes exhibit intense blue emission at room temperature in the solid state, which are attributed to π^*-π transition centered on the ligands.

关键词: Gallium complex, Crystal structure, Luminescent property

Abstract:

Key words: Gallium complex, Crystal structure, Luminescent property

ZHOU Guang-peng, YANG Yu-lin, FAN Rui-qing. Syntheses, Crystal Structures and Luminescent Properties of Three New Gallium Complexes Containing Pyridine-2,6-dicarboxylic Acid[J]. 高等学校化学研究, 2012, 28(6): 936-941.

参考文献

[1] Bandoli G., Dolmella A., Tisato F., Porchia M., Refosco F., Coord. Chem. Rev., 2009, 253, 56

[2] Goodwin J. C., Teat S. J., Heath S. L., Angew. Chem. Int. Ed., 2004, 43, 4037

[3] Akutsu-Sato A., Akutsu H., Turner S. S., Day P., Probert M. R., Howard J. A. K., Akutagawa T., Takeda S., Nakamura T., Mori T., Angew. Chem. Int. Ed., 2005, 44, 292

[4] Jurisson S., Berning D., Jia W., Da M., Chem. Rev., 1993, 93, 1137

[5] Santos M. A., Gil M., Marques S., Gano L., Cantinho G., Chaves S., J. Inorg. Biochem., 2002, 92, 43

[6] Cheetham A. K., Férey G., Loiseau T., Angew. Chem. Int. Ed., 1999, 38, 3268

[7] Walton R. I., Millange F., Loiseau T., O’Hare D., Férey G., Angew. Chem. Int. Ed., 2000,39, 4552

[8] Lin C. H., Wang S. L., Li K. H., J. Am. Chem. Soc., 2001, 123, 4649

[9] Yang L., Bi M. H., Fan Y., Zhang D., Dong Y. Q., Feng S. H., Inorg. Chim. Acta, 2005, 358, 4505

[10] Xue M., Li Y. X., Huang L., Qiu S. L., Chem. J. Chinese Universities, 2011, 32(3), 515

[11] Kuppler R. J., Timmons D. J., Fang Q. R., Li J. R., Makal T. A., Young M. D., Yuan D. Q., Zhao D., Zhuang W. J., Zhou H. C., Coord. Chem. Rev., 2009, 253, 3042

[12] Ye B. H., Tong M. L., Chen X. M., Coord. Chem. Rev., 2005, 249, 545

[13] Wu L. L., He R., Wei Z., Song H. H., Chem. Res. Chinese Universities, 2011, 27(5), 724

[14] Tong Y. P., Lin Y. W., Synth. Met., 2010, 160, 1662

[15] Chan W. T. K., Eisler D. J., Wright D. S., CrystEngComm, 2008, 10, 1315

[16] Crispini A., Ghedini M., Franco I. D., Aiello I., Deda M. L., Godbert N., Bellusci A., Dalton Trans., 2008, 1186

[17] Minasian S. G., Arnold J., Dalton Trans., 2009, 106

[18] Gerasko O. A., Mainicheva E. A., Naumov D. Y., Kuratieva N. V., Sokolov M. N., Fedin V. P., Inorg. Chem., 2005, 44, 4133

[19] Sofetis A., Raptopoulou C. P., Terzis A., Zafiropoulos T. F., Inorg. Chim. Acta, 2006, 359, 3389

[20] Samanamú C. R., Lococo P. M., Richards A. F., Inorg. Chim. Acta, 2007, 360, 4037

[21] Zanias S., Raptopoulou C. P., Terzis A., Zafiropoulos T. F., Inorg. Chem. Commun., 1999, 2, 48

[22] Papaefstathiou G. S., Manessi S., Raptopoulou C. P., Behrman E. J., Zafiropoulos T. F., Inorg. Chem. Commun., 2004, 7, 69

[23] Kagkelari A., Bekiari V., Stathatos E., Papaefstathiou G. S., Raptopoulou C. P., Zafiropoulos T. F., Lianos P., J. Lumin., 2009, 129, 578

[24] Baker R. J., Jones C., Kloth M., Mills D. P., New J. Chem., 2004, 28, 207

[25] Beachley O. T., Gardinier J. R. Jr., Churchill M. R., Organometallics, 2003, 22, 1145

[26] Viola N. A., Rarig R. S. Jr., Ouellette W., Doyle R. P., Polyhedron, 2006, 25, 3457

[27] Volkringer C., Loiseau T., Guillou N., Férey G., Elka?m E., Solid State Sci., 2009, 11, 1507

[28] Darensbourg D. J., Billodeaux D. R., C. R. Chimie, 2004, 7, 755

[29] Liu M. S., Yu Q. Y., Cai Y. P., Su C. Y., Lin X. M., Zhou X. X., Cai J. W., Cryst. Growth Des., 2008, 8, 4083

[30] Cai Y. P., Yu Q. Y., Zhou Z. Y., Hu Z. J., Fang H. C., Wang N., Zhan Q. G., Chen L., Su C. Y., CrystEngComm, 2009, 11, 1006

[31] Hu X., Zeng Y. F., Chen Z., San?udo E. C., Liu F. C., Ribas J., Bu X. H., Cryst. Growth Des., 2009, 9, 421

[32] Huang K. L., Liu X., Chen X., Wang D. Q., Cryst. Growth Des., 2009, 9, 1646

[33] Chen X. L., Gou L., Hu H. M., Fu F., Han Z. X., Shu H. M., Yang M. L., Xue G. L., Du C. Q., Eur. J. Inorg. Chem., 2008, 2, 239

[34] Aghabozorg H., Ramezanipour F., Kheirollahi P. D., Saei A. A., Shokrollahi A., Shamsipur M., Manteghi F., Soleimannejad J., Sharif M. A., Z. Anorg. Allg. Chem., 2006, 632, 147

[35] Rafizadeh M., Nemati A., Derikvand Z., Acta Cryst., 2008, E64, m1298

[36] Sheldrick G. M., SMART and SAINT Software Package, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1996

[37] Sheldrick G. M., SHELXL Program, Version 5.1, Siemens Industrial Automation, Inc., Madison, WI, 1997

[38] Papaefstathiou G. S., Sofetis A., Raptopoulou C. P., Terzis A., Spyroulias G. A., Zafiropoulos T. F., J. Mol. Struct., 2007, 837, 5

[39] Shi X., Zhu G. S., Fang Q. R., Wu G., Tian G., Wang R. W., Zhang D. L., Xue M., Qiu S. L., Eur. J. Inorg. Chem., 2004, 1, 185

[40] Fan R. Q., Zhang Y. J., Yin Y. B., Su Q., Yang Y. L., Hasi W., Syn. Met., 2009, 159, 1106

Syntheses, Crystal Structures and Luminescent Properties of Three New Gallium Complexes Containing Pyridine-2,6-dicarboxylic Acid

Syntheses, Crystal Structures and Luminescent Properties of Three New Gallium Complexes Containing Pyridine-2,6-dicarboxylic Acid

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