Synthesis and Structures of Two New Molybdophosphates

高等学校化学研究 ›› 2003, Vol. 19 ›› Issue (3): 257-262.

Synthesis and Structures of Two New Molybdophosphates

LIN Zheng-zhong^1,2, ZHANG Han-hui^1,2, HUANG Chang-cang¹, SUN Rui-qing¹, YANG Qi-yu¹

1. Chemistry Department, Fuzhou University, Fuzhou 350002, P. R. China;
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002, P. R. China

收稿日期:2002-07-05 出版日期:2003-08-24 发布日期:2011-08-06
基金资助:
Supported by FPNSFC(E0110013, K02028) and Fuzhou University XKJ(QD)-0139.

Synthesis and Structures of Two New Molybdophosphates

LIN Zheng-zhong^1,2, ZHANG Han-hui^1,2, HUANG Chang-cang¹, SUN Rui-qing¹, YANG Qi-yu¹

1. Chemistry Department, Fuzhou University, Fuzhou 350002, P. R. China;
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002, P. R. China

Received:2002-07-05 Online:2003-08-24 Published:2011-08-06
Supported by:
Supported by FPNSFC(E0110013, K02028) and Fuzhou University XKJ(QD)-0139.

摘要/Abstract

摘要： A one-dimension solid and a two-dimension solid consisting of polyoxoanions bridged by {CoO₃N₂} and {CoO₄} groups respectively have been synthesized by the hydrothermal method and structurally characterized by X-Ray crystallography. Each structure has the [(PO₄)₄Mo₆O₁₅]^12- cluster that is commonly observed in many molybdophosphates. In compound 1, [(PO₄)₄Mo₆O₁₅]^12- clusters are linked by {CoO₃N₂} groups to form a chain-like structure, and the chains are hydrogen-bonded into a network. Compound 2 is a layer structure with channnels constructed from [(PO₄)₄Mo₆O₁₅]^12- clusters and {CoO₄} groups, the organic molecules and the lattice water molecules are distributed disorderly in the interlamellar region and form strong hydrogen bonds with inorganic framework. The IR and the fluorescent spectra were investigated and discussed.

关键词: Hydrothermal, Molybdophosphates, Crystal structure

Abstract: A one-dimension solid and a two-dimension solid consisting of polyoxoanions bridged by {CoO₃N₂} and {CoO₄} groups respectively have been synthesized by the hydrothermal method and structurally characterized by X-Ray crystallography. Each structure has the [(PO₄)₄Mo₆O₁₅]^12- cluster that is commonly observed in many molybdophosphates. In compound 1, [(PO₄)₄Mo₆O₁₅]^12- clusters are linked by {CoO₃N₂} groups to form a chain-like structure, and the chains are hydrogen-bonded into a network. Compound 2 is a layer structure with channnels constructed from [(PO₄)₄Mo₆O₁₅]^12- clusters and {CoO₄} groups, the organic molecules and the lattice water molecules are distributed disorderly in the interlamellar region and form strong hydrogen bonds with inorganic framework. The IR and the fluorescent spectra were investigated and discussed.

Key words: Hydrothermal, Molybdophosphates, Crystal structure

LIN Zheng-zhong, ZHANG Han-hui, HUANG Chang-cang, SUN Rui-qing, YANG Qi-yu. Synthesis and Structures of Two New Molybdophosphates[J]. 高等学校化学研究, 2003, 19(3): 257-262.

LIN Zheng-zhong, ZHANG Han-hui, HUANG Chang-cang, SUN Rui-qing, YANG Qi-yu. Synthesis and Structures of Two New Molybdophosphates[J]. Chemical Research in Chinese Universities, 2003, 19(3): 257-262.

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Synthesis and Structures of Two New Molybdophosphates

Synthesis and Structures of Two New Molybdophosphates

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