Preparation of MnO2 Loaded Hydrothermal Carbon-coated Electrospun PAN Fiber Membranes for Highly Efficient Adsorption and Separation of Cationic Dye

doi:10.1007/s40242-020-0215-y

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (6): 1292-1301.doi: 10.1007/s40242-020-0215-y

Preparation of MnO₂ Loaded Hydrothermal Carbon-coated Electrospun PAN Fiber Membranes for Highly Efficient Adsorption and Separation of Cationic Dye

WANG Yuannan¹, LI Wenyan¹, CHAO Shen¹, LI Yanzi², LI Xiang¹, HE Dayong¹, WANG Ce¹

1. Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Teaching Experimental Center, Hebei Normal University for Nationalities, Chengde 067000, P. R. China

收稿日期:2020-06-29 修回日期:2020-08-13 出版日期:2020-12-01 发布日期:2020-08-20
通讯作者: LI Xiang E-mail:xiangli@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.51773082).

Preparation of MnO₂ Loaded Hydrothermal Carbon-coated Electrospun PAN Fiber Membranes for Highly Efficient Adsorption and Separation of Cationic Dye

WANG Yuannan¹, LI Wenyan¹, CHAO Shen¹, LI Yanzi², LI Xiang¹, HE Dayong¹, WANG Ce¹

1. Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Teaching Experimental Center, Hebei Normal University for Nationalities, Chengde 067000, P. R. China

Received:2020-06-29 Revised:2020-08-13 Online:2020-12-01 Published:2020-08-20
Contact: LI Xiang E-mail:xiangli@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.51773082).

摘要/Abstract

摘要： Hydrothermal carbonaceous materials and MnO₂ have been proved to be promising adsorbents to remove organic dyes from wastewater. In this study, flexible MnO₂ loaded hydrothermal carbon-coated electrospun poly-acrylonitrile(AC/MnO₂/PAN) fiber membranes were fabricated by a facile one-step hydrothermal method and activated by NaOH solution. The composite fibers exhibited large adsorption capacity toward cationic dyes and excellent mechanical properties. The adsorption performance can be fitted well with pseudo-second-order model and Langmuir isotherm model. The maximum adsorption for methylene blue(MB), methyl violet(MV) and malachite green(MG) are 1173.27,1106.31 and 1129.89 mg/g, respectively, according to Langmuir fitting. The AC/MnO₂/PAN fiber membrane also showed satisfactory performances for selective adsorption and recyclability. In addition, based on selective adsorption, the AC/MnO₂/PAN fiber membranes that are repulsive to the anionic dye methyl orange(MO) can separate the MB/MO mixture solution by dynamic filtration. Thus, this work not only provides a facile strategy to fabricate large capacity adsorbents, but also demonstrates the potential applications in the dye wastewater treatment field.

关键词: Carbon, MnO₂, One-step hydrothermal, Electrospinning, Adsorption, Cationic dye

Abstract: Hydrothermal carbonaceous materials and MnO₂ have been proved to be promising adsorbents to remove organic dyes from wastewater. In this study, flexible MnO₂ loaded hydrothermal carbon-coated electrospun poly-acrylonitrile(AC/MnO₂/PAN) fiber membranes were fabricated by a facile one-step hydrothermal method and activated by NaOH solution. The composite fibers exhibited large adsorption capacity toward cationic dyes and excellent mechanical properties. The adsorption performance can be fitted well with pseudo-second-order model and Langmuir isotherm model. The maximum adsorption for methylene blue(MB), methyl violet(MV) and malachite green(MG) are 1173.27,1106.31 and 1129.89 mg/g, respectively, according to Langmuir fitting. The AC/MnO₂/PAN fiber membrane also showed satisfactory performances for selective adsorption and recyclability. In addition, based on selective adsorption, the AC/MnO₂/PAN fiber membranes that are repulsive to the anionic dye methyl orange(MO) can separate the MB/MO mixture solution by dynamic filtration. Thus, this work not only provides a facile strategy to fabricate large capacity adsorbents, but also demonstrates the potential applications in the dye wastewater treatment field.

Key words: Carbon, MnO₂, One-step hydrothermal, Electrospinning, Adsorption, Cationic dye

WANG Yuannan, LI Wenyan, CHAO Shen, LI Yanzi, LI Xiang, HE Dayong, WANG Ce. Preparation of MnO₂ Loaded Hydrothermal Carbon-coated Electrospun PAN Fiber Membranes for Highly Efficient Adsorption and Separation of Cationic Dye[J]. 高等学校化学研究, 2020, 36(6): 1292-1301.

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Preparation of MnO₂ Loaded Hydrothermal Carbon-coated Electrospun PAN Fiber Membranes for Highly Efficient Adsorption and Separation of Cationic Dye

Preparation of MnO₂ Loaded Hydrothermal Carbon-coated Electrospun PAN Fiber Membranes for Highly Efficient Adsorption and Separation of Cationic Dye

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