Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)2

doi:10.1007/s40242-014-4188-6

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (6): 991-996.doi: 10.1007/s40242-014-4188-6

Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂

MA Xitong, XING Na, WU Qiong, XU Liting, XING Yongheng

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, P. R. China

收稿日期:2014-05-14 修回日期:2014-07-07 出版日期:2014-12-01 发布日期:2014-11-20
通讯作者: XING Na, XING Yongheng E-mail:scarllet_na@163.com;xingyongheng2000@163.com
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21306073, 21371086) and the Science and Technology Fund for Outstanding Young Talents in Dalian, China(No.2012J21DW007).

Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂

MA Xitong, XING Na, WU Qiong, XU Liting, XING Yongheng

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, P. R. China

Received:2014-05-14 Revised:2014-07-07 Online:2014-12-01 Published:2014-11-20
Contact: XING Na, XING Yongheng E-mail:scarllet_na@163.com;xingyongheng2000@163.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21306073, 21371086) and the Science and Technology Fund for Outstanding Young Talents in Dalian, China(No.2012J21DW007).

摘要/Abstract

摘要：

The catalytic activity of VO(acac)₂ for the cyclohexane(Cy) oxidation was studied. The effects of various parameters, such as the amounts of H₂O₂, HNO₃, H₂O and Cy were investigated. The highest total turnover number(TON) is 234, which can be increased to 353, 342 and 403, respectively with the adding of o-phthalic, m-phthalic or p-phthalic acid. A reaction mechanism was also supposed primarily.

关键词: VO(acac)₂, Cyclohexane oxidation, Mechanism, Phthalic acid, Additive

Abstract:

Key words: VO(acac)₂, Cyclohexane oxidation, Mechanism, Phthalic acid, Additive

MA Xitong, XING Na, WU Qiong, XU Liting, XING Yongheng. Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂[J]. 高等学校化学研究, 2014, 30(6): 991-996.

MA Xitong, XING Na, WU Qiong, XU Liting, XING Yongheng. Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂[J]. Chemical Research in Chinese Universities, 2014, 30(6): 991-996.

参考文献

[1] Pokutsa A., Fliunt O., Kubaj Y., Pacze?niak T., Blonarz P., Prystanskiy R., Muzart J., Makitra R., Zaborovskyi A., Sobkowiak A., J. Mol. Catal. A, 2011, 347, 15
[2] Serinyel Z., Herbinet O., Frottier O., Dirrenberger P., Warth V., Glaude P. A., Battin-Leclerc F., Combust. Flame, 2013, 160, 2319
[3] Huang G., Liu S. Y., Wang A. P., Guo Y. A., Zhou H., Catal. Commun., 2007, 8, 1183
[4] Einaga H., Futamura S., Appl. Catal. B, 2005, 60, 49
[5] Xing N., Xu L. T., Bai F. Y., Shan H., Xing Y. H., Shi Z., Inorg. Chim. Acta, 2014, 409, 360
[6] Wan L. J., Zhang C. S., Li Z., Xing N., Shan H., Xing Y. H., Inorg. Chem., 2012, 51, 6517
[7] Mac Leod T. C. O., Kopylovich M. N., Guedes da Silva M. F. C., Mahmudov K. T., Pombeiro A. J. L., Appl. Catal. A, 2012, 15, 439
[8] Xing N., Shan H., Tian X., Yao Q., Xu L. T., Xing Y. H., Shi Z., Dalton Trans., 2013, 42, 359
[9] Ren D. X., Xing N., Shan H., Chen C., Cao Y. Z., Xing Y. H., Dalton Trans., 2013, 42, 5379
[10] Martins L. M. D. R. S., Martins A., Alegria E. C. B. A., Carvalho A. P., Pombeiro A. J. L., Appl. Catal. A, 2013, 464, 43
[11] Grivani G., Bruno G., Rudbari H. A., Khalaji A. D., Pourteimouri P., Inorg. Chem. Commun., 2012, 18, 15
[12] Alsalim T. A., Hadi J. S., Ali O. N., Abbo H. S., Titinchi S. J. J., Chem. Cent. J., 2013, 7, 3
[13] Xing N., Shan H., Zhao H. Y., Xing Y. H., J. Coord. Chem., 2012, 65, 898
[14] Pokutsa A., Kubaj Y., Zaborovskyi A., Maksym D., Muzart J., Sobkowiak A., Appl. Catal. A, 2010, 390, 190
[15] Zhu Y. J., Li J., Xie X. F., Yang X. G., Wu Y., J. Mol. Catal. A, 2006, 246, 185
[16] Kobayashi H., Yamanaka I., J. Mol. Catal. A, 2008, 294, 37
[17] Battioni P., Renaud J. P., Bartoli J. F., Reina-Artiles M., Fort M., Mansuy D., J. Am. Chem. Soc., 1988, 110, 8462
[18] Sheu C., Richert S. A., Cofré P., Ross J. B., Sobkowiak A., SawyerD. T., Kanofsky J. R., J. Am. Chem. Soc., 1990, 112, 1936
[19] Barton D. H. R., Bévière S. D., Chavasiri W., Csuhai E., Doller D., Liu W., J. Am. Chem. Soc., 1992, 114, 2147
[20] Shul'pin G. B., Attanasio D., Suber L., J. Catal., 1993, 142, 147
[21] Kulikova V. S., Gritsenko O. N., Shteinman A. A., Mendeleev Commun., 1996, 6, 119
[22] Süss-Fink G., Stanislas S., Shul'pin G. B., Nizova G. V., Stoeckli-Evans H., Neels A., Bobillier C., Claude S., Dalton Trans., 1999, 18, 3169
[23] Süss-Fink G., Stanislas S., Shul'pin G. B., Nizova G. V., Appl. Organomet Chem., 2000, 14, 623
[24] Süss-Fink G., Gonzalez L., Shul'pin G. B., Appl. Catal. A, 2001, 217, 111
[25] Chen K., Que L., J. Am. Chem. Soc., 2001, 123, 6327
[26] Gekhman A. E., Stolyarov I. P., Ershova N. V., Moiseeva N. I., Moiseev I. I., Dokl. Akad. Nauk, 2001, 378, 639
[27] Pillai U. R., Sahle-Demessie E., New J. Chem., 2003, 27, 525
[28] Joseph T., Hartmann M., Ernst S., Halligudi S. B., J. Mol. Catal. A, 2004, 207, 129
[29] Si T. K., Chowdhury K., Mukherjee M., Bera D. C., Bhattacharyya R., J. Mol. Catal. A, 2004, 219, 241
[30] Kozlov Y. N., Romakh V. B., Kitaygorodskiy A., Buglyó P., Süss-Fink G., Shul'pin G. B., J. Phys. Chem. A, 2007, 111, 736
[31] Silva T. F. S., Alegria E. C. B. A., Martins L. M. D. R. S., Pombeiro A. J. L., Adv. Synth. Catal., 2008, 350, 706
[32] Silva T. F. S., Leoda T. C. O. M., Martins L. M. D. R. S., Guedes da Silva M. F. C., Schiavon M. A., Pombeiro A. J. L., J. Mol. Catal. A, 2013, 367, 52
[33] Carvalho N. M. F., Horn Jr. A., Antunes O. A. C., Appl. Catal. A, 2006, 305, 140
[34] Kirillova M. V., Kozlov Y. N., Shul'pin L. S., Lyakin O. Y., Kirillov A. M., Talsi E. P., Pombeiro A. J. L., Shul'pin G. B., J. Catal., 2009, 268, 26
[35] Kirillova M. V., Kirillov A. M., Guedes da Silva M. F. C., Pombeiro A. J. L., Eur. J. Inorg. Chem., 2008, 22, 3423
[36] Kirillov A. M., Haukka M., Guedes da Silva M. F. C., Pombeiro A. J. L., Eur. J. Inorg. Chem., 2005, 11, 2071
[37] Shul'pin G. B., J. Mol. Catal. A, 2005, 227, 247
[38] Shul'pin G. B., Matthes M. G., Romakh V. B., Barbosa M. I. F., Aoyagi J. L. T., Mandelli D., Tetrahedron, 2008,64, 2143
[39] Kirillova M. V., Kuznetsov M. L., Romakh V. B., Shul'pin L. S., Silva J. J. R. F., Pombeiro A. J. L., Shul'pin G. B., J. Catal., 2009, 267, 140

Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂

Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂

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