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高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (6): 987-990.doi: 10.1007/s40242-014-4199-3

• Articles • 上一篇    下一篇

Facile Fabrication and Optical Properties of Nanostructural PbSe Films

LIU Meng, QI Xiaofei, WU Xionggang, ZHANG Hengning   

  1. Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
  • 收稿日期:2014-05-26 修回日期:2014-07-25 出版日期:2014-12-01 发布日期:2014-09-22
  • 通讯作者: LIU Meng E-mail:lm3333@126.com
  • 基金资助:

    Supported by the Science and Technology Foundation of the Science and Technology on Combustion and Explosion Laboratory of China(No.9140c3506).

Facile Fabrication and Optical Properties of Nanostructural PbSe Films

LIU Meng, QI Xiaofei, WU Xionggang, ZHANG Hengning   

  1. Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
  • Received:2014-05-26 Revised:2014-07-25 Online:2014-12-01 Published:2014-09-22
  • Contact: LIU Meng E-mail:lm3333@126.com
  • Supported by:

    Supported by the Science and Technology Foundation of the Science and Technology on Combustion and Explosion Laboratory of China(No.9140c3506).

摘要:

PbSe films with different nanostructures, such as nanoparticles, nanohollows and hierarchical structures, can be synthesized by adjusting the current density and the reaction temperature via a convenient and efficient electrochemical route in the absence of hard template and surfactant. The calculated band gaps of the prepared PbSe nanoparticles and nanohollows were about 0.32 and 0.43 eV, respectively. This suggests that quantum size effect in nanohollows greatly influences their band gap. This preparation method possesses remarkable advantages, such as low cost, high efficiency and easy preparation, which are very suitable for preparing nanomaterials.

关键词: Thin film, PbSe, Electrodeposition, Nanostructural material, Optical property

Abstract:

PbSe films with different nanostructures, such as nanoparticles, nanohollows and hierarchical structures, can be synthesized by adjusting the current density and the reaction temperature via a convenient and efficient electrochemical route in the absence of hard template and surfactant. The calculated band gaps of the prepared PbSe nanoparticles and nanohollows were about 0.32 and 0.43 eV, respectively. This suggests that quantum size effect in nanohollows greatly influences their band gap. This preparation method possesses remarkable advantages, such as low cost, high efficiency and easy preparation, which are very suitable for preparing nanomaterials.

Key words: Thin film, PbSe, Electrodeposition, Nanostructural material, Optical property