Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves

doi:10.1007/s40242-022-1407-4

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (1): 1-8.doi: 10.1007/s40242-022-1407-4

• Reviews • 下一篇

Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves

ZHANG Xiaosi^1,2, YANG Miao¹, TIAN Peng¹, LIU Zhongmin¹

1. National Engineering Laboratory for Methanol-to-Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

收稿日期:2021-10-07 修回日期:2021-12-07 出版日期:2022-02-01 发布日期:2022-01-20
通讯作者: YANG Miao, LIU Zhongmin E-mail:yangmiao@dicp.ac.cn;liuzm@dicp.ac.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.21991090, 21991091, 22171259) and the Innovation Research Foundation of Dalian Institute of Chemical Physics, Chinese Academy of Sciences(No.DICP I201909).

Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves

ZHANG Xiaosi^1,2, YANG Miao¹, TIAN Peng¹, LIU Zhongmin¹

1. National Engineering Laboratory for Methanol-to-Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2021-10-07 Revised:2021-12-07 Online:2022-02-01 Published:2022-01-20
Contact: YANG Miao, LIU Zhongmin E-mail:yangmiao@dicp.ac.cn;liuzm@dicp.ac.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21991090, 21991091, 22171259) and the Innovation Research Foundation of Dalian Institute of Chemical Physics, Chinese Academy of Sciences(No.DICP I201909).

摘要/Abstract

摘要： Aluminophosphate(AlPO) and silicoaluminophosphate(SAPO) molecular sieves are an important class of open-framework crystalline materials with wide applications thanks to their molecular-scale selectivity, moderate/strong acidity and excellent (hydro)thermal stability. In recent decades, the manufacturing of new microporous solids with ordered structures has been widely investigated and many effective methods have been developed, which enriches the material types and broadens their applications beyond the traditional use as catalysts and adsorbents. However, the development on the synthesis of AlPO/SAPO molecular sieves is still insufficient and lags behind the needs of applications. Herein, we summarize the work on the seed-assisted synthesis of AlPO/SAPO molecular sieves compared with the zeolite synthetic system, aiming to prompt the synthesis and application of AlPO/SAPO molecular sieves.

关键词: Seed-assisted synthesis, AIPO/SAPO molecular sieve, Crystallization mechanism

Abstract: Aluminophosphate(AlPO) and silicoaluminophosphate(SAPO) molecular sieves are an important class of open-framework crystalline materials with wide applications thanks to their molecular-scale selectivity, moderate/strong acidity and excellent (hydro)thermal stability. In recent decades, the manufacturing of new microporous solids with ordered structures has been widely investigated and many effective methods have been developed, which enriches the material types and broadens their applications beyond the traditional use as catalysts and adsorbents. However, the development on the synthesis of AlPO/SAPO molecular sieves is still insufficient and lags behind the needs of applications. Herein, we summarize the work on the seed-assisted synthesis of AlPO/SAPO molecular sieves compared with the zeolite synthetic system, aiming to prompt the synthesis and application of AlPO/SAPO molecular sieves.

Key words: Seed-assisted synthesis, AIPO/SAPO molecular sieve, Crystallization mechanism

ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves[J]. 高等学校化学研究, 2022, 38(1): 1-8.

ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves[J]. Chemical Research in Chinese Universities, 2022, 38(1): 1-8.

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Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves

Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves

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