Hydrothermal Synthesis and Crystal Structure of a Highly Reduced Mixed Molybdenum-vanadium Polyoxometalate with Phosphorus-centered [Ni(phen)<sub>3</sub>]2H<sub>2</sub>·[Pmo<sub>4</sub><sup>Ⅴ</sup>Mo<sub>4</sub><sup>Ⅵ</sup>V<sub>6</sub><sup>Ⅳ</sup>M<sub>2</sub>M<sub>44</sub>]<sup>5-</sup>·4H<sub>2</sub>O(M=0.78Mo<sup>Ⅴ</sup>+0.22V<sup>Ⅳ</sup>)

Hydrothermal Synthesis and Crystal Structure of a Highly Reduced Mixed Molybdenum-vanadium Polyoxometalate with Phosphorus-centered [Ni(phen)₃]2H₂·[Pmo₄^ⅤMo₄^ⅥV₆^ⅣM₂M₄₄]^5-·4H₂O(M=0.78Mo^Ⅴ+0.22V^Ⅳ)

SUN Ying-hua, DING Hong, XU Ji-qing, LI Yong, LI Guang-hua

Chemical Research in Chinese Universities . 2005, (3): 368 -371 .