Co-loading Pd and CeO2 on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction

doi:10.1007/s40242-024-4194-2

Abstract

Abstract: The methane dry reforming (DRM) reaction can convert CO₂ and CH₄, both of which contribute to climate change, into syngas, which holds great significance in mitigating specific environmental issues stemming from the greenhouse effect. Nonetheless, the challenges that persist include the substantial energy consumption and the catalyst's susceptibility to deactivation, both of which necessitate solutions. Herein, we developed a catalyst, PdCe/S1, featuring small-sized Pd species and CeO₂ stabilized on pure silicon zeolite (silicalite-1), which is employed in the DRM reaction. It can achieve 97% CH₄ conversion and 98% CO₂ conversion at 750 °C, surpassing binary Pd/CeO₂ and Pd/S1 catalysts. The small size of CeO₂ stabilized by silicalite-1 promotes oxygen defects formation and enhances the CO₂ adsorption capacity. The introduction of silicalite-1 further enhances the interaction between Pd and CeO₂, boosting DRM performance.

Key words: Dry reforming of methane, CeO₂, Zeolite

XU Jing, ZHANG Rui, WANG Ke, WANG Xiao, SONG Shuyan, ZHANG Hongjie. Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction[J]. Chemical Research in Chinese Universities, 2025, 41(1): 15-20.

References

[1] Tian S., Yan F., Zhang Z., Jiang J., Sci. Adv., 2019, 5, eaav5077.
[2] Ji G., Yao J. G., Clough P. T., da Costa J. C. D., Anthony E. J., Fennell P. S., Wang W., Zhao M., Energ. Environ. Sci., 2018, 11, 2647.
[3] Liu Y., Chen Y., Gao Z., Zhang X., Zhang L., Wang M., Chen B., Diao Y., Li Y., Xiao D., Wang X., Ma D., Shi C., Appl. Catal. B, 2022, 307, 121202.
[4] Wang R., Li T., Gao R., Qin J., Li M., Guo Y., Song Y., Chem. Res. Chinese Universities, 2023, 39, 246.
[5] Alyea E. C., He D., Wang J., Appl. Catal. A: Gen., 1993, 104, 77.
[6] Liu Z., Grinter D. C., Lustemberg P. G., Nguyen-Phan T. D., Zhou Y., Luo S., Waluyo I., Crumlin E. J., Stacchiola D. J., Zhou J., Carrasco J., Busnengo H. F., Ganduglia-Pirovano M. V., Senanayake S. D., Rodriguez J. A., Angew. Chem. Int. Ed., 2016, 55, 7455.
[7] Zhang Z., Yang Z., Liu L., Wang Y., Kawi S., Adv. Energ. Mater., 2023, 13, 2301852.
[8] Zhang F., Gutiérrez R. A., Lustemberg P. G., Liu Z., Rui N., Wu T., Ramírez P. J., Xu W., Idriss H., Ganduglia-Pirovano M. V., Senanayake S. D., Rodriguez J. A., ACS Catal., 2021, 11, 1613.
[9] Pakhare D., Spivey J., Chem. Soc. Rev., 2014, 43, 7813.
[10] Xu H., Zhang L., Wang H., Zhang S., Li W., Wang X., Song S., Wang D., Shi Z., Chem. Res. Chinese Universities, 2023, 39, 948.
[11] Foppa L., Margossian T., Kim S. M., Müller C., Copéret C., Larmier K., Comas-Vives A., J. Am. Chem. Soc., 2017, 139, 17128.
[12] Bitter J. H., Seshan K., Lercher J. A., J. Catal., 1998, 176, 93.
[13] Yan X., Hu T., Liu P., Li S., Zhao B., Zhang Q., Jiao W., Chen S., Wang P., Lu J., Fan L., Deng X., Pan Y. X., Appl. Catal. B, 2019, 246, 221.
[14] Wang K., Zhang R., Wang H., Zhang L., Wang Z., Wang X., Song S., Zhang H., Chem. Res. Chinese Universities, 2024, 40, 970.
[15] Wu X., Wang X., Zhang L., Wang X., Song S., Zhang H., Angew. Chem. Int. Ed., 2024, 63, e202317594.
[16] Lin S., Li Z., Li M., Fuel, 2023, 333, 126369.
[17] Li X., Pereira-Hernández X. I., Chen Y., Xu J., Zhao J., Pao C.-W., Fang C. Y., Zeng J., Wang Y., Gates B. C., Liu J., Nature, 2022, 611, 284.
[18] Chen J., Zhang Y., Zhang Z., Hou D., Bai F., Han Y., Zhang C., Zhang Y., Hu J., J. Mater. Chem. A, 2023, 11, 8540.
[19] Bruix A., Rodriguez J. A., Ramírez P. J., Senanayake S. D., Evans J., Park J. B., Stacchiola D., Liu P., Hrbek J., Illas F., J. Am. Chem. Soc., 2012, 134, 8968.
[20] Jin H., Xu D., Tian C., Yue Y., Hua W., Gao Z., Chem. Res. Chinese Universities, 2022, 38, 1547.
[21] Ha H., Yoon S., An K., Kim H. Y., ACS Catal., 2018, 8, 11491.
[22] Sun Q., Wang N., Fan Q., Zeng L., Mayoral A., Miao S., Yang R., Jiang Z., Zhou W., Zhang J., Zhang T., Xu J., Zhang P., Cheng J., Yang D. C., Jia R., Li L., Zhang Q., Wang Y., Terasaki O., Yu J., Angew. Chem. Int. Ed., 2020, 59, 19450.
[23] Wang N., Sun Q., Bai R., Li X., Guo G., Yu J., J. Am. Chem. Soc., 2016, 138, 7484.
[24] Wang C., Jie X., Qiu Y., Zhao Y., Al-Megren H. A., Alshihri S., Edwards P. P., Xiao T., Appl. Catal. B, 2019, 259, 118019.
[25] Wang N., Qian W., Chu W., Wei F., Catal. Sci. Technol., 2016, 6, 3594.
[26] Yang W., Polo-Garzon F., Zhou H., Huang Z., Chi M., Meyer H., Yu X., Li Y., Wu Z., Angew. Chem. Int. Ed., 2023, 62, e202217323.
[27] Guo M., Meng Q., Chen W., Meng Z., Gao M.-L., Li Q., Duan X., Jiang H. L., Angew. Chem. Int. Ed., 2023, 62, e202305212.
[28] Li S., Xu Y., Chen Y., Li W., Lin L., Li M., Deng Y., Wang X., Ge B., Yang C., Yao S., Xie J., Li Y., Liu X., Ma D., Angew. Chem. Int. Ed., 2017, 56, 10761.
[29] Li L., Xu J., Liang X., Wu X., Wang X., Song S., Zhang H., Chem. Res. Chinese Universities, 2023, 39, 921.
[30] Wang G., Mu X., Tan R., Pan Z., Li J., Zhan Q., Fu R., Song S., Li L., ACS Catal., 2023, 13, 11666.
[31] Parastaev A., Muravev V., Huertas Osta E., van Hoof A. J. F., Kimpel T. F., Kosinov N., Hensen E. J. M., Nat. Catal., 2020, 3, 526.
[32] Chang K., Wang T., Chen J. G., Appl. Catal. B, 2017, 206, 704.
[33] Zhu Q., Zhou H., Wang L., Wang L., Wang C., Wang H., Fang W., He M., Wu Q., Xiao F. S., Nat. Catal., 2022, 5, 1030.
[34] Qian L., Cai W., Zhang L., Ye L., Li J., Tang M., Yue B., He H., Appl. Catal. B, 2015, 164, 168.

Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	HU Chao, FU Wenhua, YUAN Zhiqing, LIU Chuang, WANG Zhendong, YANG Weimin. Direct Synthesis of UOS Zeolite Using a Simple and Commercially Available Organic Structure-directing Agent [J]. Chemical Research in Chinese Universities, 2025, 41(1): 113-120.
[2]	SHEN Xueyuan, QI Guodong, LIANG Jiawei, WANG Ruichen, XU Jun, DENG Feng. Unveiling the Mechanism of Glycerol Oxidation to Lactic Acid on Pt/Sn-MFI Zeolite: an In situ Solid-state NMR Study [J]. Chemical Research in Chinese Universities, 2024, 40(6): 935-942.
[3]	HUANG Yitong, WANG Yaquan, LIU Wenrong, BU Lingzhen, QU Liping, CHU Kailiang, GUO Niandong, ZHANG Xian, SU Xuemei, LI Yaoning, SANG Juncai. Synthesis of LSX Using Seed-iteration Approach with High N₂ Adsorption Capacity for Air Separation [J]. Chemical Research in Chinese Universities, 2024, 40(6): 1192-1200.
[4]	LIU Pei, WU Qinming, CHEN Zhenghai, XIAO Feng-Shou. Recent Advances in the Synthesis of Zeolites from Solid Wastes [J]. Chemical Research in Chinese Universities, 2024, 40(4): 646-656.
[5]	ZHENG Mingdan, CHEN Ya, LIU Zhan, LYU Jiamin, YE Bo, SUN Ming-Hui, CHEN Li-Hua, SU Bao-Lian. Hierarchically Macroporous Zeolite ZSM-5 Microspheres for Efficient Catalysis [J]. Chemical Research in Chinese Universities, 2024, 40(4): 704-711.
[6]	XIAO Mingjiao, LI Di, WEI Yanze, HE Yilei, WANG Zumin, YU Ranbo. Boosting the Activity and Stability of the Photoreduction of Diluted CO₂ by Copper Oxide Decorated CeO₂ Hetero-shells [J]. Chemical Research in Chinese Universities, 2024, 40(3): 513-520.
[7]	HAN Xiaoyang, XIA Huicong, TU Weifeng, WEI Yifan, XUE Dongping, LI Minhan, YAN Wenfu, ZHANG Jia-Nan, HAN Yi-Fan. Zeolite-confined Fe-site Catalysts for the Hydrogenation of CO₂ to Produce High-value Chemicals [J]. Chemical Research in Chinese Universities, 2024, 40(1): 78-95.
[8]	QU Ziqiang, ZHANG Tianjun, YIN Xichen, ZHANG Junyi, XIONG Xiaoyun, and SUN Qiming. Zeolite-encaged Ultrasmall Pt-Zn Species with Trace Amount of Pt for Efficient Propane Dehydrogenation [J]. Chemical Research in Chinese Universities, 2023, 39(6): 870-876.
[9]	FU Zerui, WANG Shu, YU Haohan, NIE Meilin, FENG Xilan, ZUO Xintao, FU Lichao, LIU Dapeng, ZHANG Yu. CeO₂ Supported on Reduced Graphene Oxide as Li-O₂ Battery Cathode [J]. Chemical Research in Chinese Universities, 2023, 39(4): 636-641.
[10]	JIN Huan, XU Ding, TIAN Chao, YUE Yinghong, HUA Weiming, GAO Zi. Insights into Promoting Effect of Sm on Catalytic Performance of the CeO₂/Beta Catalyst in Direct Conversion of Bioethanol to Propylene [J]. Chemical Research in Chinese Universities, 2022, 38(6): 1547-1552.
[11]	HE Lulu, CHEN Xin, REN Yuanhang, YUE Bin, TSANG Shik Chi Edman, HE Heyong. Improving Catalytic Stability and Coke Resistance of Ni/Al₂O₃ Catalysts with Ce Promoter for Relatively Low Temperature Dry Reforming of Methane Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1032-1040.
[12]	XIAO Peiwen, LI Hui, WANG Pingmei, LIU Bolun, JING Wendan, HE Lipeng, WANG Runwei, HAN Xue, ZHANG Zongtao, QIU Shilun, LUO Jianhui. Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1083-1088.
[13]	CHENG Dajun, and MENG Xiangju. Recent Advances of Beta Zeolite in the Volatile Organic Compounds(VOCs) Elimination by the Catalytic Oxidations [J]. Chemical Research in Chinese Universities, 2022, 38(3): 716-722.
[14]	LIU Yifeng, WANG Liang, and XIAO Feng-Shou. Selective Oxidation of Methane into Methanol Under Mild Conditions [J]. Chemical Research in Chinese Universities, 2022, 38(3): 671-676.
[15]	LUAN Huimin, WU Qinming, ZHANG Jian, WANG Yeqing, MENG Xiangju, XIAO Feng-Shou. Sustainable Synthesis of Core-Shell Structured ZSM-5@Silicalite-1 Zeolite [J]. Chemical Research in Chinese Universities, 2022, 38(1): 136-140.