Face-directed Strategy for the Construction of Polyoxovanadate-based Metal-Organic Tetrahedra

doi:10.1007/s40242-023-2335-7

Chemical Research in Chinese Universities ›› 2023, Vol. 39 ›› Issue (6): 954-959.doi: 10.1007/s40242-023-2335-7

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Face-directed Strategy for the Construction of Polyoxovanadate-based Metal-Organic Tetrahedra

CHEN Huiping^1,2, GONG Yaru¹, CHU Qiangqiang^1,2, PANG Xiao^1,2, HUANG Xiaojing^1,2, TIAN Xudong^1,2, YANG Weiting^1,2, PAN Qinhe^1,2, SU Zhongmin^1,3, and WANG Xinlong¹

1. Key Laboratory of Advanced Materials of Tropical Island Resources, Ministry of Education, School of Science, Hainan University, Haikou 570228, P.R. China;
2. School of Chemical Engineering and Technology, Hainan University, Haikou 570228, P.R. China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China

Received:2022-12-10 Online:2023-12-01 Published:2023-11-18
Contact: GONG Yaru, PAN Qinhe, WANG Xinlong E-mail:gongyr@hainanu.edu.cn;panqinhe@163.com;wangxl824@nenu.edu.cn
Supported by:
This work was supported by the Natural Science Foundation of Hainan Province, China (Nos.221QN169, 221QN171), the National Natural Science Foundation of China (No.22101067), the Innovation Program for Young Scientific and Technological Talents of Hainan Association of Science and Technology, China(No.QCQTXM202207), the Start-up Research Foundation of Hainan University, China (No.RZ2100003143), the Science and Technology Special Fund of Hainan Province, China (No.ZDYF2022SHFZ298), the International Science & Technology Cooperation Program of Hainan Province, China (No.GHYF2022006), the Specific Research Fund of the Innovation Platform for Academicians of Hainan Province, China (No.YSPTZX202321) and the Innovation Platform for Academicians of Hainan Province, China.

Abstract

Abstract: Polyoxometalate-based metal-organic polyhedra (MOPs) were of particular concern because of the various exquisite building blocks and the suitable constructional characteristics. To further understand the design and particularity of polyoxovanadate-based MOPs, (NH₂Me)₈{[V₆O₆(OCH₃)₉(C₆H₅PO₃)]₄· (BPT)₄}·2DMF (HNU-74) and (NH₂Me)₁₂{[V₆O₆(OCH₃)₉(C₆H₅PO₃)]₄· (HBCBAIP)₄}(SO₄)₂·MeOH·DMF (HNU-75) were constructed by a face-directed synthesis strategy. Both structures were assembled with four secondary building units as vertexes and four organic ligands served as faces. Different from HNU-74, HNU-75 showed a carboxyl group free during the coordination process, resulting in the pore channels being blocked and the free carboxyl group linking outwards, paving the way for the formation of the 3D structure. Due to the pore channels of HNU-74, the adsorption of I2 was studied and the adsorption capacity was 148 mg/g.

Key words: Metal-organic polyhedron, Face-directed strategy, Tetrahedral structure, Iodine adsorption

CHEN Huiping, GONG Yaru, CHU Qiangqiang, PANG Xiao, HUANG Xiaojing, TIAN Xudong, YANG Weiting, PAN Qinhe, SU Zhongmin, and WANG Xinlong. Face-directed Strategy for the Construction of Polyoxovanadate-based Metal-Organic Tetrahedra[J]. Chemical Research in Chinese Universities, 2023, 39(6): 954-959.

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Face-directed Strategy for the Construction of Polyoxovanadate-based Metal-Organic Tetrahedra

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