Chemical Research in Chinese Universities ›› 1996, Vol. 12 ›› Issue (2): 188-193.
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WU Qing, LU Ze-jian, CHEN Xue-xin, SONG Yang-han
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Supported by the National Natural Science Foundxtion of Chinx and the Science Research Foundatiunof Zhongshan University.
Abstract: A change of the polymerization mechanism from living ring-opening metathesis polymerization (ROMP) into coordination polymerization by converting the titanacyclobutane attached to a polynorbornene(PNBE)chain into titanocene alkoxcidehas been used to the synthesis of poly (NBE-b-ethylene).
Key words: Norbornene-ethylene block copolymer, Ring-opening metatbe,is polymerization, Coordination polymerization, Living polymerization, Titanacyclobutane
WU Qing, LU Ze-jian, CHEN Xue-xin, SONG Yang-han. Synthesis of Norbornene－Ethylene Block Copolymer by the Polymerization Mechanism Conversion[J]. Chemical Research in Chinese Universities, 1996, 12(2): 188-193.
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