Application of the Reactions of Ferrocene(Ⅰ) Saltswith Bis [dicarbonyl (η5-cyclopentadienyl) iron]and Bis [dicarbonyl (η4-butadiene) cobalt]Complexes to Organic Synthesis

Chemical Research in Chinese Universities ›› 1994, Vol. 10 ›› Issue (4): 280-284.

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Application of the Reactions of Ferrocene(Ⅰ) Saltswith Bis [dicarbonyl (η⁵-cyclopentadienyl) iron]and Bis [dicarbonyl (η⁴-butadiene) cobalt]Complexes to Organic Synthesis

TAO Ke, WU Le, Wurenqimug, YANG Wan-zheng

Department of Chemistry, Inner Mongolian University, Hohhot, 010021

Received:1993-12-04 Online:1994-12-24 Published:2011-08-17
Supported by:
Supported by the Research Fund of the Natural Science of Inner Mongolia and Nation.

Abstract

Abstract: Complexes[(η⁵-C₅H₅)Fe (CO)₂L]⁺BF₄^-(Ⅱ)[L=PPh₃,P(OPH)₃,P(OC₂H₅)₃,pyridine, 3-acetyl-pyridine, 4-methyl-pyridine, phenyl cyanide, quinoline] and[(η⁴-C₄H₆)Co(CO)₂L]⁺BF(Ⅱ)[L=PPh₃,P(OPH)₃,P(OC₂H₅)₃],were respec-tively produced in the reactions of[(η⁵-C₅H₅)Fe (CO)₂]₂ and [(η⁴-C₄H₅)Co(CO)₂]₂with Cp₂FeBF₄ in the presence of the ligands.Some characteristics of these reac-tions were discussed and all the complexes were identified by IR and ¹H NMR spec-troscopy.These complexes are air-stable and the preparative metliods are simple.

Key words: Organic syntliesis, Ferrocene salts, Complexes

TAO Ke, WU Le, Wurenqimug, YANG Wan-zheng . Application of the Reactions of Ferrocene(Ⅰ) Saltswith Bis [dicarbonyl (η⁵-cyclopentadienyl) iron]and Bis [dicarbonyl (η⁴-butadiene) cobalt]Complexes to Organic Synthesis[J]. Chemical Research in Chinese Universities, 1994, 10(4): 280-284.

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Application of the Reactions of Ferrocene(Ⅰ) Saltswith Bis [dicarbonyl (η⁵-cyclopentadienyl) iron]and Bis [dicarbonyl (η⁴-butadiene) cobalt]Complexes to Organic Synthesis

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