Electrochemical Studies of Eight New Divalent Transition Metal Benzenesulphonate Ternary Complexes with 1,10-Phenanthroline

Abstract

Abstract: The electrochemical properties of eight new divalent transition metal benzenesulphonate complexes with 1,10-phenanthroline in different solvents and supporting electrolytes were investigated by means of cyclic voltammetry(CV). Based on the CV data the influences of various coordination modes on the electrochemical behavior of the complexes were discussed. The diffusion coefficient D_c and rate constant k_s of those complexes in DMF systems were estimated according to CV and the results show that these processes were all quasi-reversible.

Key words: Benzenesulphonate, 1,10-Phenanthroline, Transition metal complex, Cyclic voltammetry

LU Yao, GUO Li-ping, MA Jian-fang, YANG Jin, WU Dong-mei. Electrochemical Studies of Eight New Divalent Transition Metal Benzenesulphonate Ternary Complexes with 1,10-Phenanthroline[J]. Chemical Research in Chinese Universities, 2004, 20(6): 694-697.

[1]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid [J]. Chemical Research in Chinese Universities, 2018, 34(1): 8-12.
[2]	Melek HAJJI, Taha GUERFEL. Crystal Structure, Vibrational Studies, Optical Properties and TG-DTA Investigations of a New Chlorocadmate Templated by 1-Methylimidazolium [J]. Chemical Research in Chinese Universities, 2016, 32(2): 253-260.
[3]	WANG Ruixin, WANG Hongjing, WANG Xiaogang, LEI Caiping, SHI Xiaohui. Immobilization of Transition-metal Hydroxamates on Polystyrene Resins: Effective Biomimetic Heterogeneous Catalysts for Aerobic Oxidation of Ethylbenzene [J]. Chemical Research in Chinese Universities, 2015, 31(5): 835-840.
[4]	XU Huanhuan, WANG Xueliang, CHEN Rong, YU Zhangyu. Voltammetric Determination of Epinephrine in the Presence of Uric Acid Based on Aminated Graphene and Ag NPs Hybrid Membrane Modified Electrode [J]. Chemical Research in Chinese Universities, 2014, 30(2): 205-210.
[5]	AN Jing, LI Ji-ping, CHEN Wen-xia, YANG Chun-xia, HU Fang-di, WANG Chun-ming. Electrochemical Study and Application on Shikonin at Poly(diallyldimethylammonium chloride) Functionalized Graphene Sheets Modified Glass Carbon Electrode [J]. Chemical Research in Chinese Universities, 2013, 29(4): 798-805.
[6]	MALYSHEV Victor, GAB Angelina, POPESCU Ana-Maria, CONSTANTIN Virgil. Electroreduction of Tungsten Oxide(VI) in Molten Salts with Added Metaphosphate [J]. Chemical Research in Chinese Universities, 2013, 29(4): 771-775.
[7]	SUN Yi, ZHANG Mi-lin, HAN Wei, LI Mei, YANG Yu-sheng. Electrochemical Formation of Al-Li Alloys by Codeposition of Al and Li from LiCl-KCl-AlF₃ Melts at 853 K [J]. Chemical Research in Chinese Universities, 2013, 29(2): 324-328.
[8]	ZHAO Bang-tun, LI Jia-jia, ZHOU Zhen, YAN Zhen-ning, ZHU Wei-min. Synthesis and Electrochemical Behavior of Electroactive Bistetrathiafulvalene-attached Thiacalix[4]arene Assemblies [J]. Chemical Research in Chinese Universities, 2012, 28(5): 828-832 .
[9]	LI Li and SHI Ke-ying*. Electrooxidation of Nitric Oxide at a Glass Carbon Electrode Modified with Functionalized Single-walled Carbon Nanotube [J]. Chemical Research in Chinese Universities, 2010, 26(6): 1025-1030.
[10]	LI Li-jun*, CHENG Long-jun, CAI Zhuo, LAN Su-mei, GUO Xiao-fei and LI Yan-qing. Determination of Metamizole Sodium by Cyclic Voltammetry Under Microwave Activation [J]. Chemical Research in Chinese Universities, 2010, 26(4): 537-540.
[11]	YU Shi-jun, XUE Bin, WANG Jian-ya*, SUN Jian and SHEN Zhi-qiu. Electrochemical Oxidation of Chlorimuron-ethyl on Ti/SnO₂-Sb₂O₅/PbO₂ Anode for Waste Water Treatment [J]. Chemical Research in Chinese Universities, 2010, 26(4): 630-635.
[12]	ZHAO Xi, LI Bin, XU Shan-sheng, SONG Hai-bin and WANG Bai-quan* . Synthesis, Structure, and Ring-opening Metathesis Polymerization of η⁵-Pentamethylcyclopentadienyl-(η⁵-exo-tricyclo[5.2.1.0^2,6]deca-2,5,8-trien-6-yl) Iron [J]. Chemical Research in Chinese Universities, 2009, 25(5): 662-665.
[13]	YANG Tao, WANG Zeng-Jian, JIAO Kui, LI Qing-Jun. Spectroscopic Electrochemical Studies of Interaction Between Fuchsin Basic DNA [J]. Chemical Research in Chinese Universities, 2006, 22(3): 292-296.
[14]	WU Jing, LI Xiao-li, WU Xu-mei, HUAN Shuang-yan, SHEN Guo-li, YU Ru-qin. Electrochemical Detection of Clenbuterol in Pig Liver at Pyrrole-DNA Modified Boron-doped Diamond Electrode [J]. Chemical Research in Chinese Universities, 2005, 21(5): 517-521.
[15]	NIU Shu-yan, JIE Gui-fen, ZHANG Shu-sheng, LI Ying, YANG Fan. Electrochemical and Spectroscopic Studies on Interaction between Complex of Copper(Ⅱ) with Schiff Base Ligand and DNA [J]. Chemical Research in Chinese Universities, 2005, 21(2): 149-153.

Electrochemical Studies of Eight New Divalent Transition Metal Benzenesulphonate Ternary Complexes with 1,10-Phenanthroline

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments