Chemical Research in Chinese Universities ›› 2023, Vol. 39 ›› Issue (2): 228-233.doi: 10.1007/s40242-022-2140-8

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Optically Controlled Coercive Field of MAPbI3/P(VDF-TrFE) Ferroelectric Composite Films

SU Yangfan1, SUN Yiran1, ZHOU Dikui3, TANG Xiaoming2, HAN Gaorong1, REN Zhaohui1,3   

  1. 1. State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;
    2. Center of Electron Microscope, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China;
    3. Research Center for Humanoid Sensing, Zhejiang Lab, Hangzhou 311100, P. R. China
  • Received:2022-04-15 Online:2023-04-01 Published:2023-03-16
  • Contact: REN Zhaohui E-mail:renzh@zju.edu.cn
  • Supported by:
    This work was supported by the Natural Science Foundation of Zhejiang Province, China(No.LR21E020004), the National Natural Science Foundation of China (No.U1909212) and the Project of the Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, China(No.2021SX-FR007).

Abstract: Ferroelectric polymers, such as poly(vinylidene fluoride-trifluoroethylene)[P(VDF-TrFE) or PVTF] have attracted growing interest in developing flexible devices because of their excellent ferroelectricity and piezoelectricity. High coercive field(Ec) inherent to PVTF for switching its polarization, however, is not beneficial for practical memory or sensor device application. Different strategies, including irradiation and interface control, have been thus developed to reduce Ec. Despite many efforts, a facile approach to tailoring intrinsic Ec of PVTF has not been documented. In this work, an optically controlled Ec was reported, which is achieved for the first time by introducing photosensitive MAPbI3 nanocrystals into PVTF matrix. When exposed to the irradiation of 532 nm laser light, a decreased Ec of the composites can be achieved reversibly by increasing the light density. The decreased level of Ec increases as the MAPbI3 content enhanced, and a 10.7% reduction of Ec can be achieved in 15%(mass fraction) MAPbI3/PVTF samples. These results could be attributed to loading an internal stress on PVTF, which was generated by the photostriction of MAPbI3 nanocrystals. This explanation was further supported by in-situ XRD results under irradiation of 532 nm laser light. Our findings may offer the opportunity to optically modulate the ferroelectric properties of PVTF composites for optimized device performances.

Key words: Poly(vinylidene fluoride-trifluoroethylene)[P(VDF-TrFE)], MAPbI3, Photostriction, Optically controlled coercive field