In situ Preparation of Tri-Fe(III) and Bi-Cu(II) Clusters from Benzoyl Peroxide Reacting with Metal Powders

Chemical Research in Chinese Universities ›› 2009, Vol. 25 ›› Issue (5): 600-605.

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In situ Preparation of Tri-Fe(III) and Bi-Cu(II) Clusters from Benzoyl Peroxide Reacting with Metal Powders

YANG Jun-wei², ZHANG Jing², TONG Shan-ling^1*, HUANG Xiao-chun² and YAN Yan^1*

1. College of Light Industry & Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, P. R. China;
2. Department of Chemistry, Shantou University, Shantou 515063, P. R. China

Received:2009-02-04 Revised:2009-04-02 Online:2009-09-25 Published:2009-12-07
Contact: TONG Shan-ling, E-mail: tongsl@gdut.edu.cn; YAN Yan, E-mail: yanyan@gdut.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.20771073).

Abstract

Abstract:

Three crystal architectures, including one organic compound of benzoyl peroxide(1) and two clusters of tri-iron(III) and bi-cupper(II) with benzoic ligands(2 and 3), were self-assembled by an in situ redox way of benzoyl peroxide oxidants reacting with Mo, Fe and Cu powders, respectively. X-ray crystallographic results show that both the asymmetry tri-iron(III) cluster and the benzoylperoxide crystal architecture(2 and 1) with complicated 3D networks were constructed by intermolecular hydrogen-bonding interactions. Contrarily, the symmetrical bi-copper(II) cluster crystal architecture(3), only with π-π stacking between paralleled phenyl groups and without any intermolecular hydrogen-bonding interactions, only presented an 1D zigzag chain along the a-axis.

Key words: In situ redox; Benzoyl peroxide; Iron/copper cluster; Self-assembly; Benzoic acid; Paramagnetism

YANG Jun-wei, ZHANG Jing, TONG Shan-ling*, HUANG Xiao-chun and YAN Yan*. In situ Preparation of Tri-Fe(III) and Bi-Cu(II) Clusters from Benzoyl Peroxide Reacting with Metal Powders[J]. Chemical Research in Chinese Universities, 2009, 25(5): 600-605.

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In situ Preparation of Tri-Fe(III) and Bi-Cu(II) Clusters from Benzoyl Peroxide Reacting with Metal Powders

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