12-Tungstophosphates Immobilized on Chemically Modified Mesoporous Silica SBA-15

Chemical Research in Chinese Universities ›› 2005, Vol. 21 ›› Issue (3): 264-267.

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12-Tungstophosphates Immobilized on Chemically Modified Mesoporous Silica SBA-15

ZHU Jing, YOU Wan-sheng, ZHU Zai-ming, SUN Zhen-gang, ZHANG Lan-cui, GU Yuan-peng

Faculty of Chemistry and Chemical Engineering, Liaoning Normal University,Dalian 116029, P. R. China

Received:2004-05-19 Online:2005-05-24 Published:2011-08-06
Supported by:
Supported by the Dalian Municipal Science and Technology Commission and Liaoning Provincial Science and Technology Commission(No.200310592003).

Abstract

Abstract: A functionalized material, PW/SBA-15m, was prepared successfully in diluted H₂SO₄ aqueous solutions by immobilizing 12-tungstophosphates on chemically modified mesoporous silica SBA-15 and characterized by elemental analysis, FTIR, ³¹P MAS NMR, XRD and TEM. The results indicate that the framework of SBA-15 and the Keggin structure of PW₁₂O₄₀^3- were retained, and that 23%-33%(mass fraction) of PW₁₂O₄₀^3- was immobilized; the PW₁₂O₄₀^3- anions were finely dispersed on the pore wall of SBA-15. Having been leached in ethanol at 60 ℃ for 7 h, the loss of PW₁₂O₄₀^3- anions was not found.

Key words: Polyoxometalates, 12-Tungstophosphates, SBA-15, Mesoporous materials

ZHU Jing, YOU Wan-sheng, ZHU Zai-ming, SUN Zhen-gang, ZHANG Lan-cui, GU Yuan-peng. 12-Tungstophosphates Immobilized on Chemically Modified Mesoporous Silica SBA-15[J]. Chemical Research in Chinese Universities, 2005, 21(3): 264-267.

References

[1] Kozhevnikov I. V., Chem. Rev., 1998, 98, 171 [2] Kwon T., Tsigdinos G. A., Pinnavaia T. J., J. Am. Chem. Soc., 1988, 110, 3653 [3] Watanabe Y., Yamamoto K., Tatsumi T., J. Mol. Catal. A: Chem., 1999, 145, 271 [4] Gardner E., Pinnavaia T., J. Applied Catalysis A: General, 1998, 167, 65 [5] Molár A′., Keresszegi C., Trk B., Applied Catalysis A: General, 1999, 189, 217 [6] Izumi Y., Hisano K., Hida T., Applied Catalysis A: General, 1999, 181, 277 [7] Kozhevnikov I. V., Sinnema A., Jansen R. J. J., et al., Catal. Lett., 1995, 30, 241 [8] Zhang X., Le Y., Gao Z., Chem. J. Chinese Universities, 2001, 22(7), 1169 [9] Li W., Li L., Wang Z., et al., Mater. Lett., 2001, 49, 228 [10] Liu A. M., Hidajat K., Kawi S., et al., Chem. Commun., 2000, 1145 [11] Zhang W., Lu J., Han B., et al., Chem. Mater., 2003, 14, 3413 [12] Zhang M., Zu Y., Yang Y., et al., Chem. Res. Chinese Universities, 2000, 16(3), 263 [13] Han P., Liang J., Xu B., et al., Chem. Res. Chinese Universities, 2004, 20(1), 108 [14] Zhao D., Feng J., Huo Q., et al., Science, 1998, 279, 548 [15] Zhao D., Huo Q., Feng J., et al., J. Am. Chem. Soc., 1998, 120, 6024 [16] Wu X., J. Biol. Chem., 1920, 43, 189 [17] Feng G., Frywell L. Q., Wang A., et al., Science, 1997, 276, 923 [18] Diaz J. F., Balkus K. J., Bediour F., et al., Chem. Mater., 1997, 9, 61 [19] White L. D., Tripp C. P., J. Colloid Interface Sci., 2000, 232, 400 [20] Pope M. T., Varga J. R. G. M., Inorg. Chem., 1996, 57, 1249 [21] Flanigen E. M., Khatami H., Szymanski H. A., Adv. Chem. Ser., 1971, 101, 201 [22] Lefebvre F., J. Chem. Soc., Chem. Commun., 1992, 756 [23] Lim M. H., Stein A., Chem. Mater., 1999, 11, 3285 [24] Winkler H., Brikner A., Hagen V., et al., Adv. Mater., 1999, 11, 1444 [25] Zhang W., Shi J., Wang L., et al., Chem. Mater., 2000, 12, 1408 [26] Xu W., Luo Q. H., Wang H., et al., J. Phys. Chem. B, 2003, 107, 497 [27] Zhu K., Yue B., Xie S., et al., Chin. J. Chem., 2004, 22, 33

12-Tungstophosphates Immobilized on Chemically Modified Mesoporous Silica SBA-15

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