CRCU

Chemical Research in Chinese Universities ›› 2004, Vol. 20 ›› Issue (3): 262-265.

• Articles • Previous Articles     Next Articles

Investigation of Light-harvest Material: Synthesis and Characterization of Nanometer Porphyrin Trimer

SHI Ying-yan1, WANG Xing-qiao1, LI Xiang-qing2, ZHENG Wen-qi1, DING Hong1, ZHU Guang-shan1, LIU Guo-fa1   

  1. 1. College of Chemistry, Jilin University, Changchun 130023, P. R. China;
    2. School of Chemistry & Pharmaceutics, East China University of Science and Technology, Shanghai 200237, P. R. China
  • Received:2003-04-29 Online:2004-06-24 Published:2011-08-06
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.20071014).

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Cited

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Abstract: ω-Bromopropylporphyrin ether synthesized from the raction of 1,3-dibromopropane as the bridge-linked reagent and 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin (H2MHTPP) as the matrix reacts with 5, 15-di(4- hydroxyphenyl)-10, 20-diphenyl porphyrin(trans-H2DHDPP) to give the title nanometer porphyrin trimer. The characterization was carried out by means of elemental analyses, UV-Vis, IR, 1H NMR and XRD.

Key words: Nanometer porphyrin trimer, ω-Bromopropylporphyrin ether, Bridge-linking reagent