Abstract: In the study on Ca-Mg silicate crystalline glazes, we found some disequilibrated crystallization phenomena,such as non-crystallographic small angle forking and spheroidal growth, parasitism and wedging-form of crystals, dendritic growth, secondary nucleation, etc. Those phenomena possibly resulted from two factors:(1) partial temperature gradient, which is caused by heat asymmetry in the electrical resistance furnace,when crystals crystalize from silicate melt ; (2) constitutional supercooling near the surface of crystals. The disparity of disequilibrated crystallization phenomena in different main crystalline phases causes various morphological features of the crystal aggregates. At the same time, disequilibrated crystallization causes great stress retained in the crystals, which results in cracks in glazes when the temperature drops. According to the results, the authors analyzed those phenomena and displayed correlative figures and data.

Key words: Crystalline glaze, Costitutional supercooling, Heat dynamical condition, Disequilibrated crystallization, Morphological feature of crystal aggregates