Synthesis and One-dimensional Structure of Cobalt(Ⅱ) Complex [(NaOC2H5)CoL2]n

Chemical Research in Chinese Universities ›› 2003, Vol. 19 ›› Issue (4): 379-382.

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Synthesis and One-dimensional Structure of Cobalt(Ⅱ) Complex [(NaOC₂H₅)CoL₂]_n

LI Ling, GU Wen, YAN Shi-ping, CHENG Peng, LIAO Dai-zheng, JIANG Zong-hui, SHEN Pan-wen

Department of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received:2002-09-16 Online:2003-12-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20171026) and Tianjin Natural Science Foundation(No.013605811).

Abstract

Abstract: The treatment of bis(2-hydroxybenzyl)-amine(HL) with NaOH and Co(Ⅱ)(NO)₂ gives isostructural one-dimensional coordination polymers [(NaOC₂H₅)CoL₂]_n(1). The cobalt ions have an octahedral geometry and are coordinated by two crystallographically independent ligands which are further linked by μ-O_phenol bridged Co and Na atoms to give a one-dimentional structure.

Key words: Crystal structure, Sodium, Cobalt complex, One-dimension, Bis(2-hydroxybenzyl)amine

LI Ling, GU Wen, YAN Shi-ping, CHENG Peng, LIAO Dai-zheng, JIANG Zong-hui, SHEN Pan-wen. Synthesis and One-dimensional Structure of Cobalt(Ⅱ) Complex [(NaOC₂H₅)CoL₂]_n[J]. Chemical Research in Chinese Universities, 2003, 19(4): 379-382.

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Synthesis and One-dimensional Structure of Cobalt(Ⅱ) Complex [(NaOC₂H₅)CoL₂]_n

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