CRCU

Chemical Research in Chinese Universities ›› 2001, Vol. 17 ›› Issue (S1): 124-124.

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Immobilization of Homogeneous Catalysis on Phosphinated MCM-41

SHYU Shin-Guang, CHENG Sheau-Wen, TZOU Der-Lii   

  1. Institute of Chemistry, Academia Sinica, Taipei, Taiwan
  • Online:2001-12-31 Published:2016-03-14

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Abstract:

Homogeneous catalysis Rh(PPh3)3Cl immobilized on MCM-41 modified with(OEt)3Si(CH2)3PPh2 results in a stable hydrogenation catalyst with turn over frequency(TOF) three times higher than that of RH(PPh3)3C1 in the hydrogenation of cyclohexene.