Chemical Research in Chinese Universities ›› 2001, Vol. 17 ›› Issue (S1): 116-116.

• Articles • Previous Articles     Next Articles

Synthesis of Dioxa-cage Compounds as a New Probe for the Stereochemistry of the Bisadducts of p-Benzoquinone with 1,3-Cyclodienes

WU Hsien-Jen, TSAO Ching-Bo, TSAI Ting-Yueh   

  1. Department of Applied Chemistry, Chiao Tung University, Hsinchu, Taiwan, China
  • Online:2001-12-31 Published:2016-03-14

Abstract:

π-Facial stereoselectivety in Diels-alder reactions and their synthetic applications have attracted considerable attention in recent years.In the Diels-Alder reaction of the cyclopentadiene-quinone cycloadduct 1 with cycloalkadiene,four bisadducts with different stereochemistry could potentially result endo-anti-endo 2,endo-anii-exo 3,endo-syn-exo 4,and endosyn-etido 5.