CRCU

Chemical Research in Chinese Universities ›› 1995, Vol. 11 ›› Issue (1): 45-49.

• Articles • Previous Articles     Next Articles

Studies on Solid State Reactions of Coordination Compounds (LXXI)──Solid State Reactions of o-Aminobenzoic Acid withCopper (Ⅱ) Acetate and Formate at Room Temperature

ZHENG Li-min, LIN Jian-jun, FU Yan, XIN Xin-quan   

  1. Department of Chemistry, Manjing University, Naiijing, 210008
  • Received:1994-03-15 Online:1995-01-24 Published:2011-08-17

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Abstract: Solid state reactions of o-aminobenzoic acid (HOAB) with Cu (OAc)2·H2O,Cu(HCOO)2·4H2O, anhydrous Cu(OAc)2 and Cu (HCOO)2 at room or close toroom temperature have been investigated.The product Cu(OAB)2 with a high yieldwas synthesized very conveniently compared witb the solution phase method.Thekinetic behavior was studied by means of the isothermal electrical conductivity mea-surement.The reactivity was found to decrease in the order : Cu(OAc)2· H2O>Cu(OAc)2>Cu(HCOO)2·4H2O>Cu(HCOO)2, which was attributable to the crystalstructures of the copper salts.

Key words: Solid state reaction, o-Aminobenzoic acid, Copper acetate, Copper formate, Electrical conductivity