Synthesis and Structure of(NH4)2 [V2O4(OCH2COO)2]

Chemical Research in Chinese Universities ›› 1994, Vol. 10 ›› Issue (2): 102-106.

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Synthesis and Structure of(NH₄)₂ [V₂O₄(OCH₂COO)₂]

ZHOU Zhao-hui, WANG Jinzhi, WAN Hui-lin, TSAl Khi-rui

Department of Chemistry, Xiamen University, Xianien, 361005

Received:1993-01-16 Online:1994-04-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Houndation of China.

Abstract

Abstract: Dimeric ammonium(glycollate)dioxovanadium (NH₄)₂[V₂O₄(OCH₂COO)₂]has been prepared.The complex crystallizes in triclinic space group P1 with unitcell parameters: a = 0.6124(1)nm, b= 0.6952 (1)nm, c= 0.8449 (1)nm, α=66.08 (1),β=64.21(1),γ= 78.01(1)°V=0.2958 nm³, Z=1, R=0.041.Thedimer contains a quasicentrosymmetric planar four-membered V₂O₂ ring with twoexocyclic glycollate entities coordinated by the oxygen atoms of hydroxy-and car-boxy late ligands.

Key words: Hydroxycarboxylate, Vanadium complex, Molecular structure

ZHOU Zhao-hui, WANG Jinzhi, WAN Hui-lin, TSAl Khi-rui. Synthesis and Structure of(NH₄)₂ [V₂O₄(OCH₂COO)₂][J]. Chemical Research in Chinese Universities, 1994, 10(2): 102-106.

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Synthesis and Structure of(NH₄)₂ [V₂O₄(OCH₂COO)₂]

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