Chemical Research in Chinese Universities ›› 1989, Vol. 5 ›› Issue (2): 158-163.
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Qiu Dongxu, Wang Yanfeng, Cai Mengshen
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Abstract: l-α-biaomo-2,3,4,6-tetra-O-acetyl-D-giucopyranose reacts with Grignard eagents prepared frorn the acnvated magnesium under very mild condition to ellord C-glucosides in a very high yield compared with Grignard Reagent prepared from usual method.β-anomer predominates in the reaction, mixture The configuration of anomers was assigned by 13C NMR spectra.
Key words: C-Glucosides, Grignard reagent, Activated magnesium, Anomers
Qiu Dongxu, Wang Yanfeng, Cai Mengshen . Synthesis of C-Glucosides from Grignard Reagents Prepared by Activated Magnesium[J]. Chemical Research in Chinese Universities, 1989, 5(2): 158-163.
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