Chemical Research in Chinese Universities ›› 1989, Vol. 5 ›› Issue (2): 138-146.

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The Reactions of 1-Acetothiosemicarbazidc with P(NR23 PC13 and PCI5

Zhang Jingling, Xu Wei   

  1. Institute of Organic Synthesis, Huazhong Aormal University, Wuhan
  • Received:1988-11-14 Online:1989-04-24 Published:2011-09-09

Abstract: A Series of new heterocyciophosphorus compounds were synthesizec oy cyclocondensa-tion of 1-acetothiosemicarbazide with P(NR2)3.The further reaction of these compounds with P(NR2)3 gave different compounds depending upon different reaction conditions.The 1-acetothiosemicarbazide can also condense with PCl3 and PCl5 similarly, The reaction mechanism, the spectral properties and chemical properties of these products were also studied and discussed.

Key words: Triazaphosphole, Tris(dialkylamino)phosphine, Thiosemicarbazide