Chemical Research in Chinese Universities ›› 1986, Vol. 2 ›› Issue (2): 32-37.
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Song Licheng, Hu Qingmei, Wang Jitao
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Abstract: Fourteen new PPh3 substituted Fe-Sclusters, with general formula (μ-RS)(μ-R'S)Fe2(CO)5 PPh3, have been synthesized by reaction of unsymmetrical type of bis(μ-alkylthio ) hexacarbonyldiirons with triphenylphosphine.Based on the discussion of influence of PPh3 on VCOand alkyl spacial orientation of PPh3 in clusters has also been established.
Song Licheng, Hu Qingmei, Wang Jitao . STUDIES ON SUBSTITUTION OF C=O IN BIS(μ-ALKYLTHIO)-HEXACARBONYLDI-IRONS----THE SYNTHESIS AND STRUCTURES OF(μ-RS)(μ-R'S)Fe2(CO)5Ph3[J]. Chemical Research in Chinese Universities, 1986, 2(2): 32-37.
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