Chemical Research in Chinese Universities ›› 1985, Vol. 1 ›› Issue (1): 25-31.

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Calorimetric Study on LaNi4M(M=Ni,Cu,Fe)-H Systems

Shen Panwen, Wang Genshi, Song Deying, Lu Shuqin   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1984-04-02 Online:1985-06-24 Published:2011-09-07

Abstract: The relative partial molar enthalpies and the partial molar free energiesof hydrogen dissolved in LaNi5,LaNi4Cu,and LaNi4Fe were measured respectively by acalorimetric system at 298.3K,and the partial molar entropies were also calculated By X-ray diffraction analysis the unit cell volumes Vwere calculated.It was found that both and vary with Vaccording to the following linear relations