Supported Recyclable Metal-free Frustrated Lewis Pair Catalyst for Catalytic Hydrogenation of Substituted Pyridines to Piperidines

doi:10.1007/s40242-024-4129-y

Chemical Research in Chinese Universities ›› 2024, Vol. 40 ›› Issue (4): 682-689.doi: 10.1007/s40242-024-4129-y

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Supported Recyclable Metal-free Frustrated Lewis Pair Catalyst for Catalytic Hydrogenation of Substituted Pyridines to Piperidines

MA Shaohua^1,2, TANG Zhiyong^1,2

1. CAS Key Laboratory for Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2024-05-20 Online:2024-08-01 Published:2024-07-24
Contact: TANG Zhiyong,zytang@nanoctr.cn E-mail:zytang@nanoctr.cn
Supported by:
This work was supported by the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB36000000), the National Key R&D Program of China (Nos. 2021YFA1200302, 2022YFA1205400) and the National Natural Science Foundation of China (Nos. 92356304, 92056204).

Abstract

Abstract: The construction of heterogeneous frustrated Lewis pairs (FLPs) catalysts is crucial for realizing highly efficient and recyclable pyridines catalytic hydrogenation. In this work, we prepared a recyclable heterogenous FLPs catalyst CMP-BF with conjugated microporous polymer CMP-ethynyl as the support via self-catalyzed 1,1-carboboration reaction with commercial Lewis acid B(C₆F₅)₃. The as-synthesized CMP-BF demonstrates superior heterogenous catalytic hydrogenation performance (conversion> 99%), and considerable stability (84% conversion after three cycles) in recyclable hydrogenation of 2,6-phenylpyridine. This work provides insights into the fabrication and catalytic application of recyclable heterogenous FLP catalysts.

Key words: Pyridine hydrogenation, Frustrated Lewis pair, Conjugated microporous polymer

MA Shaohua, TANG Zhiyong. Supported Recyclable Metal-free Frustrated Lewis Pair Catalyst for Catalytic Hydrogenation of Substituted Pyridines to Piperidines[J]. Chemical Research in Chinese Universities, 2024, 40(4): 682-689.

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Supported Recyclable Metal-free Frustrated Lewis Pair Catalyst for Catalytic Hydrogenation of Substituted Pyridines to Piperidines

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