Design and Synthesis of NiO@Co3O4@ZSM-5 Heterogeneous Multitask Hollow Structures for Tandem Catalysis

doi:10.1007/s40242-024-4055-z

Chemical Research in Chinese Universities ›› 2024, Vol. 40 ›› Issue (3): 529-535.doi: 10.1007/s40242-024-4055-z

• Articles • Previous Articles Next Articles

Design and Synthesis of NiO@Co₃O₄@ZSM-5 Heterogeneous Multitask Hollow Structures for Tandem Catalysis

Muhammad Waqas

Interdisciplinary Research Center for Refining and Advanced Chemicals, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

Received:2024-03-04 Online:2024-06-01 Published:2024-06-01
Contact: Muhammad Waqas,E-mail:muhammad.waqas@kfupm.edu.sa E-mail:muhammad.waqas@kfupm.edu.sa
Supported by:
The authors would like to express their gratitude to the King Fahd University of Petroleum & Minerals (KFUPM), located in Dhahran, Saudi Arabia, for the support that they have provided.

Abstract

Abstract: Precipitation and impregnation procedures unevenly distribute metals on zeolite, limiting chemical transformation in Lewis-acid, Brönsted-acid and metal-catalyzed tandem reactions. Although, heterogeneous multitask transition metals oxides@zeolites are promising catalysts for sustainable processes; nevertheless, synthesis is fascinating and complex. Herein, the construction of purposely designed multitask materials segregated in selective shells reveals the remarkable spatial organization of metals-zeolite, resulting in them being suitable for a wide range of tandem reactions. The synthesis of multi-site catalysts begins with a universal wet chemistry approach that yields nickel oxide (NiO) crystals. Then, the NiO crystals are stabilized using cationic dodecyltrimethylammonium bromide, followed by achieving cross-linking carbon growth by emulsion polymerization of glucose in hydrothermal treatment to yield uniformed NiO@carbon spheres (NiO@CSs). Next, sequential adsorption of cobalt cations and colloidal ZSM-5 (1% in H₂O, mass fraction), followed by calcination in air, yielded NiO@cobalt oxide@zeolite denoted as NiO@Co₃O₄@ZEO hollow spheres. The hollowing mechanism and materials segregation within shells are revealed by scanning and transmission electron microscopy, thermogravimetric analysis, and X-ray diffraction. The finding advances the rational synthesis of heterogenous core-shell hollow structures for various gas phase catalytic tandem reactions to yield valuable chemicals.

Key words: Multifunctional, Core-shell hollow spheres, Gas-phase reaction, Valuable chemical

Muhammad Waqas. Design and Synthesis of NiO@Co₃O₄@ZSM-5 Heterogeneous Multitask Hollow Structures for Tandem Catalysis[J]. Chemical Research in Chinese Universities, 2024, 40(3): 529-535.

References

[1] Wei Y., Li J., Zhao D., Zhao Y., Zhang Q., Gu L., Wan J., Wang D., CCS Chemistry, 2024, 6, 1.
[2] Wei Y., Zhao D., Wang D., Adv. Sci., 2023, 11, 2305408.
[3] Ge W., Chen X., Ma R., Zheng S., Shang N., Zhao X., Chem. Res. Chinese Universities, 2024, 40, 1.
[4] Waqas M., Ahmad H., Chemosphere, 2024, 350, 140968.
[5] Waqas M., Inorg. Chem., 2021, 60,13461.
[6] Zhao X., Yang M., Wang J., Wang D., Chem. Res. Chinese Universities, 2023, 39, 630.
[7] Waqas M., Iqbal S., Bahadur A., Saeed A., Raheel M., Javed M., Appl. Catal. B:Environ., 2017, 219, 30.
[8] Waqas M., Yang B., Cao L., Zhao X., Iqbal W., Xiao K., Zhu C., Zhang J., Catal. Sci.&Technol., 2019, 9, 5322.
[9] Waqas M., Wei Y., Mao D., Qi J., Yang Y., Wang B., Wang D., Nano Res., 2017, 10, 3920.
[10] Xu W., Bi R., Yang M., Wang J., Yu R., Wang D., Nano Res., 2023, 16, 12745.
[11] Mao D., Zhang Z., Yang M., Wang Z., Wang D., Int. J. Miner. Metall. Mater., 2023, 30, 581.
[12] Han W., Wei Y., Wan J., Nakagawa N., Wang D., Inorg. Chem., 2022, 61, 5397.
[13] Wei Y., Wan J., Wang J., Zhang X., Yu R., Yang N., Wang D., Small, 2021, 17, 2005345.
[14] Wang D., Wang H., Qi J., Yang N., Cui W., Wang J., Li Q., Yu X., Gu L., Yu R., Huang K., Feng S., Song S., Li J., Angew. Chem. Int. Ed., 2020, 59, 19691.
[15] Zhang H., Zhang S., Guo B., Yu L-J., Ma L., Hou B., Liu H., Zhang S., Wang J., Song J., Tang Y., Zhao X., Angew. Chem. Int. Ed., 2024, n/a:e202400285.
[16] Ma L., Hou B., Zhang H., Yuan S., Zhao B., Liu Y., Qi X., Liu H., Zhang S., Song J., Zhao X., Chem. Eng. J., 2023, 453, 139735.
[17] Wang J., Yang N., Tang H., Dong Z., Jin Q., Yang M., Kisailus D., Zhao H., Tang Z., Wang D., Angew. Chem. Int. Ed., 2013, 52, 6417.
[18] Qi J., Zhao K., Li G., Gao Y., Zhao H., Yu R., Tang Z., Nanoscale., 2014, 6, 4072.
[19] Zhou B., Waqas M., Yang B., Xiao K., Wang S., Zhu C., Li J., Zhang J., App. Surf. Sci., 2020, 506, 145004.
[20] Climent M. J., Corma A., Iborra S., Sabater M. J., ACS Catal., 2014, 4, 870.
[21] Behr A., Vorholt A. J., Ostrowski K. A., Seidensticker T., Green Chem., 2014, 16, 982.
[22] Lohr T. L., Marks T. J., Nat. Chem., 2015, 7, 477.
[23] Védrine J. C., ChemSusChem, 2019, 12, 577.
[24] de Jong K. P., Synthesis of solid catalysts John Wiley&Sons, 2009.
[25] Chen S., Takata T., Domen K., Nat. Rev. Mater., 2017, 2, 1.
[26] Hong W. T., Risch M., Stoerzinger K. A., Grimaud A., Suntivich J., Shao-Horn Y., Energy&Environ. Sci., 2015, 8, 1404.
[27] Corma A., Chem. Rev., 1997, 97, 2373.
[28] Vogt E. T. C., Weckhuysen B. M., Chem. Soc. Rev., 2015, 44, 7342.
[29] Li Y., Li L., Yu J., Chem., 2017, 3, 928.
[30] Jiao F., Li J., Pan X., Xiao J., Li H., Ma H., Wei M., Pan Y., Zhou Z., Li M., Miao S., Li J., Zhu Y., Xiao D., He T., Yang J., Qi F., Fu Q., Bao X., Science, 2016, 351, 1065.
[31] Cheng K., Zhou W., Kang J., He S., Shi S., Zhang Q., Pan Y., Wen W., Wang Y., Chem., 2017, 3, 334.
[32] Gao P., Li S., Bu X., Dang S., Liu Z., Wang H., Zhong L., Qiu M., Yang C., Cai J., Wei W., Sun Y., Nat. Chem., 2017, 9, 1019.
[33] Wang Y., Tan L., Tan M., Zhang P., Fang Y., Yoneyama Y., Yang G., Tsubaki N., ACS Catal., 2019, 9, 895.
[34] Takeuchi M., Kimura T., Hidaka M., Rakhmawaty D., Anpo M., J. Catal., 2007, 246, 235.
[35] Huang H., Huang H., Feng Q., Liu G., Zhan Y., Wu M., Lu H., Shu Y., Leung D. Y. C., Appl. Catal. B:Environ., 2017, 203, 870.
[36] Bronstein L. M., Huang X., Retrum J., Schmucker A., Pink M., Stein B. D., Dragnea B., Chem. Mater., 2007, 19, 3624.
[37] Selvin R., Hsu H.-L., Roselin L. S., Bououdina M., Synth. React. Inorg. M., 2011, 41, 1028.
[38] Roselin L. S., Selvin R., Bououdina M., Chem. Eng. Commun., 2012, 199, 221.
[39] Xiao J., Cheng K., Xie X., Wang M., Xing S., Liu Y., Hartman T., Fu D., Bossers K., van Huis MA., Nat. Mater., 2022, 21, 572.
[40] Israelachvili J. N., Intermolecular and Surface Forces, 3rd Edition, Waltham, MA. San Diego, CA, 2011.
[41] Lee J. S., Kim J. H., Lee Y. J., Jeong N. C., Yoon K. B., Angew. Chem. Int. Ed., 2007, 46, 3087.
[42] Guo R., Wang R., Ni Z., Liu X., Appl. Phys. A., 2018, 124, 623.
[43] Yin Y., Rioux R. M., Erdonmez C. K., Hughes S., Somorjai G. A., Alivisatos A. P., Science, 2004, 304, 711.
[44] Cao L., Chen D., Caruso R. A., Angew. Chem. Int. Ed., 2013, 52, 10986.

Design and Synthesis of NiO@Co₃O₄@ZSM-5 Heterogeneous Multitask Hollow Structures for Tandem Catalysis

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 0

Recommended Articles

Metrics

Comments