Design and Synthesis of Bismuth-based Metal-Organic Frameworks for Photothermal Energy Conversion

doi:10.1007/s40242-024-4037-1

Chemical Research in Chinese Universities ›› 2024, Vol. 40 ›› Issue (6): 964-969.doi: 10.1007/s40242-024-4037-1

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Design and Synthesis of Bismuth-based Metal-Organic Frameworks for Photothermal Energy Conversion

WANG Rui^1,2, WANG Ziyu², YIN Qi², LIU Haixiong², LIU Tianfu^2,3, CAO Rong^1,2,3

1. Department of Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, P. R. China;
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350108, P. R. China;
3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2024-02-22 Online:2024-12-01 Published:2024-10-26
Contact: CAO Rong,rcao@fjirsm.ac.cn E-mail:rcao@fjirsm.ac.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 22071246, 22220102005, 22272178), CAS-Iranian Vice Presidency for Science and Technology Joint Research Project (No. 121835KYSB20200034).

Abstract

Abstract: Template effect of the solvents plays a key role in metal-organic frameworks (MOFs) synthesis. In addition, Bi³⁺ has a flexible and changeable coordination configuration, which is conducive to the construction of structurally diverse MOFs. Herein, we demonstrate that these features can be integrated into two stable bismuth-based porphyrin MOFs (named PFC-100 and PFC-101) with a wide range of light absorption. Further studies demonstrate that PFC-101 with weaker interactions of adjacent porphyrin planes achieves 22.2% photothermal conversion efficiency (PTCE), 1.5-fold higher than that of PFC-100 (14.3%) under 660 nm irradiation. This study may shed light on the impact of solvent templates on the synthesis of bismuth-based MOFs, not only enriching the MOFs library but also broadening the horizon of their potential applications.

Key words: Metal-organic frameworks (MOFs), Bismuth-based MOFs, Design and synthesis, Photothermal energy conversion

WANG Rui, WANG Ziyu, YIN Qi, LIU Haixiong, LIU Tianfu, CAO Rong. Design and Synthesis of Bismuth-based Metal-Organic Frameworks for Photothermal Energy Conversion[J]. Chemical Research in Chinese Universities, 2024, 40(6): 964-969.

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Design and Synthesis of Bismuth-based Metal-Organic Frameworks for Photothermal Energy Conversion

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