A Fluorescent In (III) Metal-Organic Framework for Explosives Detection

doi:10.1007/s40242-023-3058-5

Abstract

Abstract: Anovel metal-organic framework {[In₃(TATAT)₂]·3CH₃NH₃· 7NMF·8H₂O}[JLU-MOF101, H₆TATAT=5,5’,5’’-(1,3,5-triazine- 2,4,6-triyl)tris-(azanediyl)triisophthalate, NMF=N-methyl- formamide] with cor topology has been synthesized under solvothermal conditions. The framework of JLU-MOF101 is constructed by {In(COO)₄}^- nodes and a hexacarboxylic organic ligand. JLU-MOF101 exhibits excellent fluorescence properties in N,N-dimethylformamide (DMF) solution, and its emission spectrum can be greatly overlapped with the ultraviolet absorption spectra of trinitrophenol (TNP) and 2,4-dinitrophenol (2,4-DNP). As a result, JLU-MOF101 exhibits excellent performance of fluorescence quenching for TNP and 2,4-DNP. In addition, we demonstrate the selective detection capability of JLU-MOF101 through a large number of anti-interference tests.

Key words: Selective detection, Indium metal-organic framework, Fluorescent detection, Nitroaromatic explosive

LI Wen, LIU Xinyao, LI Guanghua, and LIU Yunling. A Fluorescent In (III) Metal-Organic Framework for Explosives Detection[J]. Chemical Research in Chinese Universities, 2023, 39(6): 1005-1009.

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