A Perspective: the Technical Barriers of Zn Metal Batteries

doi:10.1007/s40242-020-9092-7

Abstract

Abstract: Energy storage will witness a leap of understanding of new battery chemistries. Considering the safety that cannot be compromised, new aqueous batteries may surface as the solutions to meet the immense market needs, where the growth of renewables is no longer limited by the lack of storage. Aqueous Zn-metal batteries are intriguing candidates to deliver the desirable properties and exhibit competitive levelized energy cost. However, the fact that most commercial Zn batteries are primary batteries states the difficulty of reversibility for the reactions of electrodes in such batteries. This article will highlight the practical needs that guide the development of storage batteries. The causes of irreversibility for both cathode and zinc metal anode are discussed, and the potential solutions for these challenges are summarized. Zn metal batteries may one day address the storage needs, and there exists a vast potential to further improve the properties of reactions in this battery.

Key words: Zn-metal battery, Storage battery, Zn-metal anode, Hydrogen evolution reaction

JI Xiulei, JIANG Heng. A Perspective: the Technical Barriers of Zn Metal Batteries[J]. Chemical Research in Chinese Universities, 2020, 36(1): 55-60.

References 43

[1]	Ji X., Energy & Environment Science, 2019, 12, 3203
[2]	Henzen V., BloombergNEF Blog, 2019, https://about.bnef.com/blog/energy-storage-investments-boom-battery-costs-halve-next-decade/
[3]	Wang X., Yasukawa E., Kasuya S., Journal of the Electrochemistry Society, 2001, 148, A1058
[4]	Zeng Z., Murugesan V., Han K. S., Jiang X., Cao Y., Xiao L., Ai X., Yang H., Zhang J. G., Sushko M. L., Liu J., Nature Energy, 2018, 3, 674
[5]	Wang J., Yamada Y., Sodeyama K., Watanabe E., Takada K., Tateyama Y., Yamada A., Nature Energy, 2018, 3, 22
[6]	Kundu D., Talaie E., Duffort V., Nazar L. F., Angewandte Chemie International Edition, 2015, 54, 3431
[7]	Delmas C., Advanced Energy Materials, 2018, 8, 1703137
[8]	Wu X., Leonard D. P., Ji X., Chemistry of Materiasl, 2017, 29, 5031
[9]	Jian Z., Luo W., Ji X., Journal of the American Chemical Society, 2015, 137, 11566
[10]	Li Z., Bommier C., Chong Z. S., Jian Z., Surta T. W., Wang X., Xing Z., Neuefeind J. C., Stickle W. F., Dolgos M., Greaney P. A., Ji X., Advanced Energy Materials, 2017, 7, 1602894
[11]	Aurbach D., Lu Z., Schechter A., Gofer Y., Gizbar H., Turgeman R., Cohen Y., Moshkovich M., Levi E., Nature, 2000, 407, 724
[12]	Lin M. C., Gong M., Lu B., Wu Y., Wang D. Y., Guan M., Angell M., Chen C., Yang J., Hwang B. J., Dai H., Nature, 2015, 520, 324
[13]	Shyamsunder A., Blanc L. E., Assoud A., Nazar L. F., ACS Energy Letter, 2019, 4, 2271
[14]	Zhang M., Song X., Ou X., Tang Y., Energy Storage Materials, 2019, 16, 65
[15]	Rodríguez-Pérez I. A., Ji X., ACS Energy Letter, 2017, 2, 1762
[16]	Zhou X., Liu Q., Jiang C., Ji B., Ji X., Tang Y., Cheng H. M., Angewandte Chemie International Edition, 2019, 58, 2
[17]	Edison T. A., Reversible Galvanic Battery, U.S. Patent 678,722, 1901
[18]	Whittingham M. S., Science, 1976, 192, 1126
[19]	Mizushima K., Jones P., Wiseman P., Goodenough J. B., Materials Research Bulletin, 1980, 15, 783
[20]	Turney D. E., Gallaway J. W., Yadav G. G., Ramirez R., Nyce M., Banerjee S., Chen-Wiegart Y. C. K., Wang J., D'Ambrose M. J., Kolhekar S., Chemistry of Materials, 2017, 29, 4819
[21]	Wu X., Xu Y., Jiang H., Wei Z., Hong J. J., Hernandez A. S., Du F., Ji X., ACS Applied Energy Materials, 2018, 1, 3077
[22]	Wang F., Borodin O., Gao T., Fan X., Sun W., Han F., Faraone A., Dura J. A., Xu K., Wang C., Nature Materials, 2018, 17, 543
[23]	Yufit V., Tariq F., Eastwood D. S., Biton M., Wu B., Lee P. D., Brandon N. P., Joule, 2019, 3, 485
[24]	Higashi S., Lee S. W., Lee J. S., Takechi K., Cui Y., Nature Communications, 2016, 7, 11801
[25]	Li S., Jiang M., Xie Y., Xu H., Jia J., Li J., Advanced Materials, 2018, 30, 1706375
[26]	Parker J. F., Pala I. R., Chervin C. N., Long J. W., Rolison D. R., Journal of the Electrochemistry Society, 2016, 163, A351
[27]	Parker J. F., Chervin C. N., Pala I. R., Machler M., Burz M. F., Long J. W., Rolison D. R., Science, 2017, 356, 415
[28]	Xu C., Li B., Du H., Kang F., Angewandte Chemie International Edition, 2012, 51, 933
[29]	Zhang N., Cheng F., Liu Y., Zhao Q., Lei K., Chen C., Liu X., Chen J., Journal of the American Chemical Society, 2016, 138, 12894
[30]	Ma L., Li N., Long C., Dong B., Fang D., Liu Z., Zhao Y., Li X., Fan J., Chen S., Advanced Functional Materials, 2019, 29, 1906142
[31]	Zhao Q., Huang W., Luo Z., Liu L., Lu Y., Li Y., Li L., Hu J., Ma H., Chen J., Science Advances, 2018, 4, e1761
[32]	Wu X., Xu Y., Zhang C., Leonard D. P., Markir A., Lu J., Ji X., Journal of the American Chemical Society, 2019, 141, 6338
[33]	Kundu D., Adams B. D., Duffort V., Vajargah S. H., Nazar L. F., Nature Energy, 2016, 1, 16119
[34]	Sun W., Wang F., Hou S., Yang C., Fan X., Ma Z., Gao T., Han F., Hu R., Zhu M., Wang C., Journal of the American Chemical Society, 2017, 139, 9775
[35]	Yadav G. G., Gallaway J. W., Turney D. E., Nyce M., Huang J., Wei X., Banerjee S., Nature Communications, 2017, 8, 14424
[36]	Zhang C., Holoubek J., Wu X., Daniyar A., Zhu L., Chen C., Leonard D. P., Rodríguez-Pérez I. A., Jiang J. X. Jiang C., Ji X, Chemical Communications, 2018, 54, 14097
[37]	Suo L., Borodin O., Gao T., Olguin M., Ho J., Fan X., Luo C., Wang C., Xu K., Science, 2015, 350, 938
[38]	Dubouis N., Lemaire P., Mirvaux B., Salager E., Deschamps M., Grimaud A., Energy & Environmental Science, 2018, 11, 3491
[39]	Zheng J., Tan G., Shan P., Liu T., Hu J., Feng Y., Yang L., Zhang M., Chen Z., Lin Y., Chem., 2018, 4, 2872
[40]	Li X., Liu L., Schlegel H. B., Journal of the American Chemical Society, 2002, 124, 9639
[41]	Dou Q., Lu Y., Su L., Zhang X., Lei S., Bu X., Liu L., Xiao D., Chen J., Shi S., Energy Storage Materials, 2019, 23, 603
[42]	Zhao J., Ren H., Liang Q., Yuan D., Xi S., Wu C., Manalastas Jr. W., Ma J., Fang W., Zheng Y., Nano Energy, 2019, 62, 94
[43]	Wu X., Markir A., Xu Y., Zhang C., Leonard D. P., Shin W., Ji X., Advanced Functional Materials, 2019, 29, 1900911