New All-solid-state Carbonate Ion-selective Electrode with Ag2CO3-BaCO3 as Sensitive Films

doi:10.1007/s40242-016-6062-1

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (4): 655-660.doi: 10.1007/s40242-016-6062-1

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New All-solid-state Carbonate Ion-selective Electrode with Ag₂CO₃-BaCO₃ as Sensitive Films

ZHAO Yue¹, HAN Chenhua², HUANG Yuanfeng¹, QIN Wenli¹, ZHANG Xiao¹, KAN Yating¹, YE Ying¹

1. Ocean College, Zhejiang University, Zhoushan 316021, P. R. China;
2. Second Institute of Oceanography, State Oceanic Administration, Hangzhou 310012, P. R. China

Received:2016-02-25 Revised:2016-05-03 Online:2016-08-01 Published:2016-05-10
Contact: HAN Chenhua E-mail:hanchenhua0127@163.com
Supported by:
Supported by the Essential Project of Zhejiang Province, China(No.2012C13008-1), the China Ocean Mineral Resources Research & Development Association Project(No.DY125-11-R-04), the Zhejiang Projects II for Postdoctoral Research Funds, China(No.14010) and the Scientific Research Fund of the Second Institute of Oceanography, State Oceanic Administration, China (No.JG1521).

Abstract

Abstract:

A new all-solid-state carbonate ion-selective electrode was fabricated via electrochemical and ion-exchange reactions with Ag nanoparticles and Ag₂CO₃-BaCO₃ as ion-to-electron transducer and ion-selective layer, respectively. This paper presented the detailed procedures of the construction of the electrode, the applications of the electrode in various experiments, and the corresponding chemical reaction principles involved. The fabricated electrode was characterized by means of scanning electron microscopy(SEM), energy dispersive spectrometer(EDS), and electrochemical analyses. The electrode exhibited stable linear responses to carbonate anions(10^-5-10^-1 mol/L) with average slope of the curve being -26.56 mV per decade, and showed negligible responses to NO₃^- , SO₄^2-, and Sal^- anions. The electrode was further used to measure the concentration of carbonate anions in boiler water. The measured concentration was lower than that determined via titration. Overall, the electrode exhibited the advantages of miniaturized size, robust construction, and compatibility with other equipment and thus could be ideally integrated into various sensor platforms to collect chemical data from industrial heat exchangers.

Key words: Ag₂CO₃-BaCO₃, Ion-selective electrode, Carbonate determination, Heat exchange water

ZHAO Yue, HAN Chenhua, HUANG Yuanfeng, QIN Wenli, ZHANG Xiao, KAN Yating, YE Ying. New All-solid-state Carbonate Ion-selective Electrode with Ag₂CO₃-BaCO₃ as Sensitive Films[J]. Chemical Research in Chinese Universities, 2016, 32(4): 655-660.

References

[1] Al-Rawaifeh A. E., Al-Shamaileh E. M., Desalination, 2007, 206, 322
[2] Sheikholeslami R., Heat Transfer Eng., 2000, 21, 34
[3] Whalley P. B., Chem. Eng. Res. Des., 1992, 70, 545
[4] Karoui H., Riffault B., Jeannin M., Kahoul A., Gil O., Ben A. M., Tlili M. M., Desalination, 2013, 311, 234
[5] Oleinik B. N., Surin V. G., Petrova O. K., Raskin A. A., High Temp., 1985, 23, 403
[6] Fan L. Y., Xie L. Z., J. Hubei Univ. Sci. Technol., 2013, 33, 21
[7] Al-Rawajfeh A. E., Desalination, 2007, 205, 124
[8] Gu Z. X., Wang G., Bai Y. Q., Song Y., Zhao Z. M., Ann. Nucl. Energy, 2015, 81, 84
[9] Al-Rawajfeh A. E., Glade H., Ulrich J., Desalination, 2005, 182, 209
[10] Neal C., Sci. Total Environ., 2001, 265, 99
[11] Tsikas D., Chobanyan-Jurgens K., Anal. Chem., 2010, 82, 7897
[12] Byrne R. H., Yao W. S., Mar. Chem., 2008, 112, 128
[13] Fletcher P. J., van Staden J. F., Anal. Chim. Acta, 2003, 485, 187
[14] Millero F. J., Lee K., Roche M., Mar. Chem., 1998, 60, 111
[15] Lueker T. J., Dickson A. G., Keeling C. D., Mar. Chem., 2000, 70, 105
[16] Dickson A. G., Millero F. J., Deep Sea Res., 1987, 34, 1733
[17] Cai W. J., Ma Y. N., Hopkinson B. M., Grottoli A. G., Warner M. E., Ding Q., Hu X. P., Yuan X. C., Schoepf V., Xu H., Han C. H., Melman T. F., Hoadley K. D., Pettay D. T., Matsui Y., Baumann J. H., Levas S., Ye Y., Wang Y. C., Nat. Commun., 2016, 7, 11144
[18] Zhan N., Huang Y., Rao Z., Zhao X. L., Chin. J. Anal. Chem., 2016, 44, 355
[19] Saleh M. B., Gaber A. A. A., Khalaf M. M. R., Tawfeek A. M., Sens. Actuat. B: Chem., 2006, 119, 275
[20] Bakker E., Pretsch E., Anal. Chem., 2002, 74, 420a
[21] Huang Y. F., Li J., Yin T. Y., Jia J. J., Ding Q., Zheng H., Chen C. T. A., Ye Y., J. Electroanal. Chem., 2015, 741, 87
[22] Pyun H. J., Chu J. H., Yoon W., Jun Y. M., Kim D. J., Bull. Korean Chem. Soc., 1999, 20, 179
[23] Rechnitz G. A., Nogle G. J., Bellinger M. R., Lees H., Clin. Chim. Acta, 1977, 76, 295
[24] Behringer C., Lehmann B., Haug J. P., Seiler K., Morf W. E., Hartman K., Simon W., Anal. Chim. Acta, 1990, 233, 41
[25] MajZurawska M., Sokalski T., Ostaszewska J., Paradowski D., Mieczkowski J., Czarnocki Z., Lewenstam A., Hulanicki A., Talanta, 1997, 44, 1641
[26] De Beer D., Bissett A., De Wit R., Jonkers H., Kohler-Rink S., Nam H., Kim B. H., Eickert G., Grinstain M., Limnol. Oceanogr. Meth., 2008, 6, 532
[27] Hanna T. A., Liu L. H., Zakharov L. N., Rheingold A. L., Watson W. H., Gutsche C. D., Tetrahedron, 2002, 58, 9751
[28] Choi Y. S., Lvova L., Shin J. H., Oh S. H., Lee C. S., Kim B. H., Cha G. S., Nam H., Anal. Chem., 2002, 74, 2435
[29] Lee H. J., Yoon I. J., Yoo C. L., Pyun H. J., Cha G. S., Nam H., Anal. Chem., 2000, 72, 4694
[30] Greenberg J. A., Meyerhoff M. E., Anal. Chim. Acta, 1982, 141, 57
[31] Radu A., Radu T., McGraw C., Dillingham P., Anastasva-Ivanova S., Diamond D., J. Serb. Chem. Soc., 2013, 78, 1729
[32] Liang R. N., Yin T. J., Qin W., Anal. Chim. Acta, 2015, 853, 291
[33] Ibrahim M. A. M., Hassan H. H., Abd El Rehim S. S., Amin M. A., J. Solid State Electrochem., 1999, 3, 380
[34] Deyhimi F., Talanta, 1999, 50, 1129
[35] Zhang Q. Z., Gao R., Xu F., Zhou Q., Jiang G. B., Wang T., Chen J. M., Hu J. T., Jiang W., Wang W., Environ. Sci. Technol., 2014, 48, 5051
[36] Li Y. W., Zhang R. M., Du L. K., Zhang Q. Z., Wang W. X., Catal. Sci. Technol., 2016, 6, 73
[37] Fibbioli M., Morf W. E., Badertscher M., De Rooij N. F., Pretsch E., Electroanal., 2000, 12, 1286
[38] Han C. H., Cai W. J., Wang Y. C., Ye Y., J. Oceanogr., 2014, 70, 425
[39] Mocak J., Bond A. M., Mitchell S., Scollary G., Pure Appl. Chem., 1997, 69, 297
[40] Bakker E., Pretsch E., Buhlmann P., Anal. Chem., 2000, 72, 1127
[41] Bobacka J., Maj-Zurawska M., Lewenstam A., Biosens. Bioelectron., 2003, 18, 245
[42] Maj-Zurawska M., Ziemianek D., Mikolajczuk A., Mieczkowski J., Lewenstam A., Hulanicki A., Sokalski T., Anal. Bioanal. Chem., 2003, 376, 524
[43] Chen L. D., Mandal D., Pozzi G., Gladysz J. A., Buehlmann P., J. Am. Chem. Soc., 2011, 133, 20869

New All-solid-state Carbonate Ion-selective Electrode with Ag₂CO₃-BaCO₃ as Sensitive Films

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