Chemical Evolution of LiCoO2 and NaHSO4·H2O Mixtures with Different Mixing Ratios During Roasting Process

doi:10.1007/s40242-016-5490-2

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (4): 674-677.doi: 10.1007/s40242-016-5490-2

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Chemical Evolution of LiCoO₂ and NaHSO₄·H₂O Mixtures with Different Mixing Ratios During Roasting Process

WANG Dahui¹, WEN Hao¹, CHEN Huaijing², YANG Yujiao¹, LIANG Hongyan¹

1. State Key Laboratory of Advance Processing and Recycling of Nonferrous Metals, Lanzhou 730050, P. R. China;
2. College of Science, Lanzhou University of Technology, Lanzhou 730050, P. R. China

Received:2015-12-16 Revised:2016-03-15 Online:2016-08-01 Published:2016-04-20
Contact: WANG Dahui E-mail:wangdh@lut.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.51264027) and the National Basic Research Program of China(No.2012CB722806).

Abstract

Abstract:

Mixtures of NaHSO₄·H₂O and LiCoO₂ extracted from spent lithium-ion batteries were prepared with molar ratios of 1:1, 1:2 and 1:3. The chemical evolution of the LiCoO₂ and NaHSO₄·H₂O mixtures during the roasting process was investigated by means of thermogravimetric analysis and differential scanning calorimetry (TG-DSC), X-ray diffraction(XRD), scanning electron microscopy(SEM), and X-ray photoelectron spectroscopy (XPS). The results show that the chemical reactions in the LiCoO₂ and NaHSO₄·H₂O mixtures proceed during the roasting process. The Li element in the product of the roasting process is in the form of LiNa(SO₄). With the increase of the proportion of NaHSO₄·H₂O in the mixtures, the Co element evolves as follows: LiCoO₂→Co₃O₄→ Na₆Co(SO₄)₄→Na₂Co(SO₄)₂. The roasting products exhibit dense structures and irregular shapes, and the bonding energy of Co increases.

Key words: Spent lithium-ion battery, LiCoO₂, Sulfating roasting, Chemical evolution

WANG Dahui, WEN Hao, CHEN Huaijing, YANG Yujiao, LIANG Hongyan. Chemical Evolution of LiCoO₂ and NaHSO₄·H₂O Mixtures with Different Mixing Ratios During Roasting Process[J]. Chemical Research in Chinese Universities, 2016, 32(4): 674-677.

References

[1] Etacheri V., Marom R., Elazari R., Salitra G., Aurbach D., Energy Environ Sci., 2011, 4, 3243
[2] Bruno S. B., Hassoun J., Sun Y. K., Energy Environ Sci., 2011, 4, 3287
[3] Jiang X., Shi N. N., Zhang Y., Cheng K., Ye K., Wang G. L., Cao D. X., Chem. J. Chinese Universities, 2015, 36(4), 739
[4] Feng G. J., Xun R. Q., Tang Z. Y., Ai H. Q., Chem. J. Chinese Universities, 2007, 28(8), 1532
[5] Dorella G., Mansur M. B., J. Power Sources, 2007, 170, 210
[6] Zeng X. L., Li J. H., J. Hazard Mater., 2014, 271, 50
[7] Grimes S. M., Donaldsonb J. D., Chaudhary A. J., Hassan M. U., Environ. Sci. Technol., 2000, 34(19), 4128
[8] Kang D. H. P., Chen M., Ogunseitan O. A., Environ. Sci. Technol., 2013, 47(10), 5495
[9] Paulino J. F., Busnardo N. G., Afonso J. C., J. Hazard Mater., 2008, 150(3), 843
[10] Shin S. M., Kim N. H., Sohn J. S., Yang D. H., Kim Y. H., Hydrometallurgy, 2005, 79(10), 172
[11] Mishra D., Kim D., Ralph D. E., Ahn J., Rhee Y., Waste Manag., 2008, 28, 333
[12] Zeng G., Deng X., Luo S., Luo X., Zou J., J. Hazard Mater., 2012, 199/200, 164
[13] Xin B., Zhang D., Zhang X., Xia Y., Wu F., Chen S., Li L., Bioresource Technol., 2009, 100, 6163
[14] Wang H. G., Friedrich B., J. Sustain. Metall., 2015, 1, 168
[15] Georgi-Maschler T., Friedrich B., Weyhe R., Heegn H., Rutz M., J. Power Sources, 2012, 207(6), 173
[16] Castillo S., Ansart F., Laberty-Robert C., Portal J., J. Power Sources, 2002, 112(1), 247
[17] Chen L., Tang X., Zhang Y., Li L., Zeng Z., Zhang Y., Hydrometallurgy, 2011, 108(1), 80
[18] Lain M., J. Power Sources, 2001, 97(3), 736
[19] Li L., Lu J., Ren Y., Zhang X. X., Chen R. J., Wu F., Amine K., J. Power Sources, 2012, 218(12), 21
[20] Li J. H., Zhong S. W., Xiong D. L., Chen H., Rare Metals, 2009, 28(4), 328
[21] Sun L., Qiu K., Waste Manag., 2012, 32(8), 1575
[22] Granata G., Moscardini E., Pagnanelli F., J. Power Sources, 2012, 206, 393
[23] Li L., Ge J., Chen R., Wu F., Chen S., Zhang X., Waste Manag., 2010, 30(12), 2615
[24] Nan J. M., Han D. M., Zuo X. X., J. Power Sources, 2005, 152(1), 278
[25] Li J., Li X., Hu Q., Wang Z., Zheng J., Wu L., Zhang L., Hydrometallurgy, 2009, 99(1/2), 7
[26] Lupi C., Pasquali M., Miner. Eng., 2003, a16(6), 537
[27] Li D. F., Wang C. Y., Yin F., Chen Y. Q., Jie X. W., Yang Y. Q., Wang J., Chin. J. Process Eng., 2009, 19(2), 264

Chemical Evolution of LiCoO₂ and NaHSO₄·H₂O Mixtures with Different Mixing Ratios During Roasting Process

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