High-pressure, High-temperature Synthesis and Properties of the Monoclinic Phase of Y2O3

doi:10.1007/s40242-016-5469-z

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (4): 545-548.doi: 10.1007/s40242-016-5469-z

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High-pressure, High-temperature Synthesis and Properties of the Monoclinic Phase of Y₂O₃

ZHANG Qian¹, WU Xiang^2,3, OVSYANNIKOV V. Sergey⁴, DONG Juncai⁵, QIN Shan³, DUBROVINSKY S. Leonid⁴, CHEN Dongliang⁵

1. Gemological Institute, China University of Geosciences, Wuhan 430074, P. R. China;
2. State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, P. R. China;
3. Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education & School of Earth and Space Sciences, Peking University, Beijing 100871, P. R. China;
4. Bayerisches Geoinstitut, Universität Bayreuth, Bayreuth D-95447, Germany;
5. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy ofSciences, Beijing 100049, P. R. China

Received:2015-12-04 Revised:2016-03-02 Online:2016-08-01 Published:2016-04-20
Contact: WU Xiang E-mail:xiang.wu@pku.edu.cn
Supported by:
Supported by the National Natural Science foundation of China(Nos.U1232204, 41473056).

Abstract

Abstract:

The monoclinic phase of Y₂O₃(B-RES)has been synthesized using a Kawai-type multi-anvil apparatus under 20 GPa at 1800 ℃. Samples of the cubic Y₂O₃(C-RES) and monoclinic Y₂O₃phases were characterized by synchrotron radiation X-ray diffraction, X-ray absorption near edge structure and Raman spectroscopy. Crystal structures of the cubic and monoclinic phases have been examined using Rietveld refinement of the X-ray diffraction data. The cubic-to-monoclinic transition of Y₂O₃ was reconstructive and irreversible. The X-ray diffraction results were further confirmed by simulation of the X-ray absorption spectra.

Key words: Y₂O₃, High pressure, Multi-anvil synthesis

ZHANG Qian, WU Xiang, OVSYANNIKOV V. Sergey, DONG Juncai, QIN Shan, DUBROVINSKY S. Leonid, CHEN Dongliang. High-pressure, High-temperature Synthesis and Properties of the Monoclinic Phase of Y₂O₃[J]. Chemical Research in Chinese Universities, 2016, 32(4): 545-548.

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High-pressure, High-temperature Synthesis and Properties of the Monoclinic Phase of Y₂O₃

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