Synthesis of Liquid-like Trisilanol Isobutyl-POSS NOHM and Its Application in Capturing CO2

doi:10.1007/s40242-015-4443-5

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (3): 484-488.doi: 10.1007/s40242-015-4443-5

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Synthesis of Liquid-like Trisilanol Isobutyl-POSS NOHM and Its Application in Capturing CO₂

BAI Haipeng, ZHENG Yaping, LI Peipei, ZHANG Aibo

School of Natural and Applied Science, Northwestern Polytechnical University, Xi'an 710072, P. R. China

Received:2014-11-26 Revised:2015-04-02 Online:2015-06-01 Published:2015-04-13
Contact: ZHENG Yaping E-mail:zhengyp@nwpu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51373137, 51373136) and the Key Project of the Graduation Design Project of Northwestern Polytechnical University of China(No.20141101).

Abstract

Abstract:

The trisilanol isobutyl polyhedral oligomeric silsesquioxane(POSS) was fabricated into liquid-like nanoparticle organic hybrid materials(NOHMs) with γ-(2,3-epoxypropoxy)propytrimethoxysilane as corona and polyetheramine M2070 as canopy, and the product was called liquid-like POSS NOHM. The liquid-like POSS NOHM has a low viscosity at room temperature without any solvent and the mass fraction of trisilanol isobutyl POSS was 23.38%. The liquid-like POSS NOHM shows great CO₂ capturing property with a capacity of 2.108 mmol/g(p_CO₂=6 MPa). The physical adsorption increased obviously with the pressure going up and it may make a difference between liquid-like POSS NOHMs and traditional monoethamolamine(MEA) based CO₂ absorbent. The recycle property was also studied. The NOHM behaved as fresh product even after 10 cycles.

Key words: Liquid-like nanoparticle organic hybrid material, Polyhedral oligomeric silsesquioxane, CO₂ capture

BAI Haipeng, ZHENG Yaping, LI Peipei, ZHANG Aibo. Synthesis of Liquid-like Trisilanol Isobutyl-POSS NOHM and Its Application in Capturing CO₂[J]. Chemical Research in Chinese Universities, 2015, 31(3): 484-488.

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Synthesis of Liquid-like Trisilanol Isobutyl-POSS NOHM and Its Application in Capturing CO₂

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