Bifunctional Salen-Cu(II) Complex as Efficient Catalyst for N-Arylation of Imidazoles and Suzuki-Miyaura Coupling Reactions

doi:10.1007/s40242-015-4437-3

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (4): 549-552.doi: 10.1007/s40242-015-4437-3

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Bifunctional Salen-Cu(II) Complex as Efficient Catalyst for N-Arylation of Imidazoles and Suzuki-Miyaura Coupling Reactions

WANG Yi, GAO Jingyi, ZHAO Mengdan, LI Jiamei

Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, P. R. China

Received:2014-11-19 Revised:2014-12-04 Online:2015-08-01 Published:2014-12-29
Contact: WANG Yi E-mail:slwangyi@126.com
Supported by:
Supported by the National Natural Science Foundation of China(No.20672054) and the Scientific Research Fund of Yunnan Provincial Department of Education, China(No.22012Z020).

Abstract

Abstract:

Bifunctional Salen-Cu(II) complex catalyzed cross-coupling reactions of aryl halids with imidazoles or phenylboronic acid reagents have been developed as practical methods for C―N and C―C bond formation. The procedure tolerates aryl halides with various functional groups(such as methoxy, acetyl, nitrile, fluoro and nitro groups) and gives the corresponding coupling products in moderate to high yields. The catalyst remained active after five successive catalytic runs without loss in performance.

Key words: Salen-Cu(II) complex, Homogenous catalysis, Cross-coupling, N-Arylation

WANG Yi, GAO Jingyi, ZHAO Mengdan, LI Jiamei. Bifunctional Salen-Cu(II) Complex as Efficient Catalyst for N-Arylation of Imidazoles and Suzuki-Miyaura Coupling Reactions[J]. Chemical Research in Chinese Universities, 2015, 31(4): 549-552.

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Bifunctional Salen-Cu(II) Complex as Efficient Catalyst for N-Arylation of Imidazoles and Suzuki-Miyaura Coupling Reactions

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