Chemical Research in Chinese Universities ›› 2014, Vol. 30 ›› Issue (2): 242-244.doi: 10.1007/s40242-014-3296-7

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Design, Synthesis and Properties of Novel C60-Crown Dyads by 1,3-Dipolar Cycloaddition

DI Xingdong1, YE Jinqi1, YANG Fafu1,2, GUO Hongyu1, YAN Xiaoyun3   

  1. 1. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, P. R. China;
    2. Fujian Key Laboratory of Polymer Materials, Fuzhou 350007, P. R. China;
    3. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
  • Received:2013-07-12 Revised:2013-08-19 Online:2014-04-01 Published:2013-09-02
  • Contact: YANG Fafu E-mail:yangfafu@fjnu.edu.cn
  • Supported by:

    Supported by the Program for Innovative Research Team in Science and Technology in Fujian Province University, China, the Fujian Natural Science Foundation of China(No.2011J01031), the Project of Fujian Provincial Department of Education, China(No.JA11044) and the Program for Excellent Young Researchers in University of Fujian Province, China(No.JA10056).

Abstract:

Based on the 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine attached to C60, two novel benzo-15-crown-5/C60 dyads with a different linking chain in each were designed and synthesized in yields of 30% and 38%, respectively. It was found that their UV-Vis absorption spectra could be regulated hypsochromically by metal ions complexed. The long and soft linking chain was favorable for cooperate interaction of crown ether unit and C60 unit.

Key words: C60, Benzo-15-crown-5, 1,3-Dipolar cycloaddition, Complexation