Facile Synthesis of Al-pillared Mesoporous Montmorillonite Assisted with Concentrated Al13 Solution

doi:10.1007/s40242-014-3271-3

Chemical Research in Chinese Universities ›› 2014, Vol. 30 ›› Issue (2): 200-204.doi: 10.1007/s40242-014-3271-3

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Facile Synthesis of Al-pillared Mesoporous Montmorillonite Assisted with Concentrated Al₁₃ Solution

ZHAO Tianqi, LI Wenjie, WANG Hongyan, MENG Fanyu

College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2013-06-26 Revised:2013-08-29 Online:2014-04-01 Published:2013-09-02
Contact: MENG Fanyu E-mail:mengfanyu@jlu.edu.cn
Supported by:
Supported by the National Oil and Gas Resources in Cooperative Innovation of Production Projects of China(No.OSR-03).

Abstract

Abstract:

Al-pillared mesoporous montmorillonite was facilely synthesized from concentrated Al₁₃ solution obtained by vacuum concentrating-ultrasonic pillaring strategy. Concentrated Al₁₃ solution could reduce the process of pillare and increase pillaring efficiency. The absolute value of layer distance could be increased by 0.96 nm via concentrated Al₁₃ solution pillare. ²⁷Al NMR indicates that Al Keggin ions of concentrated Al₁₃ are arranged in a more regular way by vacuum concentrating method. The Al-pillared mesoporous montmorillonite from concentrated Al₁₃ solution has bigger specific surface area and even pore size distribution which were characterized by X-ray diffraction(XRD) and nitrogen adsorption measurement. Furthermore the catalytic activity of Al-pillared montmorillonite loaded Ni and Mo catalysts was tested by the hydrodesulfurization of thiophene. The thiophene conversion reached 77.5%, which was higher than the corresponding value reported in the literature.

Key words: Pillared montmorillonite, Mesoporous material, Vacuum concentrating-ultrasonic

ZHAO Tianqi, LI Wenjie, WANG Hongyan, MENG Fanyu. Facile Synthesis of Al-pillared Mesoporous Montmorillonite Assisted with Concentrated Al₁₃ Solution[J]. Chemical Research in Chinese Universities, 2014, 30(2): 200-204.

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Facile Synthesis of Al-pillared Mesoporous Montmorillonite Assisted with Concentrated Al₁₃ Solution

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